On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel

A probable mechanism of the cleavage reaction of thioacetals by copper(II) sulphate adsorbed on silica gel involves: formation of a chelate between sulphur atoms and copper(II), previously coordinated with hydroxyl groups on the silica surface, and the subsequent hydrolysis promoted by hydroxyl grou...

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Detalles Bibliográficos
Autores principales: Caballero, Gerardo Manuel, Gros, Eduardo Gervasio
Publicado: 1997
Materias:
Copper(II) Sulphate
Thioacetats
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09320776_v52_n9_p1147_Caballero
http://hdl.handle.net/20.500.12110/paper_09320776_v52_n9_p1147_Caballero
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_09320776_v52_n9_p1147_Caballero
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spelling paper:paper_09320776_v52_n9_p1147_Caballero2023-06-08T15:53:07Z On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel Caballero, Gerardo Manuel Gros, Eduardo Gervasio Copper(II) Sulphate Thioacetats A probable mechanism of the cleavage reaction of thioacetals by copper(II) sulphate adsorbed on silica gel involves: formation of a chelate between sulphur atoms and copper(II), previously coordinated with hydroxyl groups on the silica surface, and the subsequent hydrolysis promoted by hydroxyl groups on the silica gel surface. Fil:Caballero, G.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1997 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09320776_v52_n9_p1147_Caballero http://hdl.handle.net/20.500.12110/paper_09320776_v52_n9_p1147_Caballero
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Copper(II) Sulphate
Thioacetats
spellingShingle Copper(II) Sulphate
Thioacetats
Caballero, Gerardo Manuel
Gros, Eduardo Gervasio
On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
topic_facet Copper(II) Sulphate
Thioacetats
description A probable mechanism of the cleavage reaction of thioacetals by copper(II) sulphate adsorbed on silica gel involves: formation of a chelate between sulphur atoms and copper(II), previously coordinated with hydroxyl groups on the silica surface, and the subsequent hydrolysis promoted by hydroxyl groups on the silica gel surface.
author Caballero, Gerardo Manuel
Gros, Eduardo Gervasio
author_facet Caballero, Gerardo Manuel
Gros, Eduardo Gervasio
author_sort Caballero, Gerardo Manuel
title On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_short On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_full On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_fullStr On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_full_unstemmed On the Mechanism of Cleavage of Thioacetals Promoted by Copper(II) Sulphate Adsorbed on Silica Gel
title_sort on the mechanism of cleavage of thioacetals promoted by copper(ii) sulphate adsorbed on silica gel
publishDate 1997
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09320776_v52_n9_p1147_Caballero
http://hdl.handle.net/20.500.12110/paper_09320776_v52_n9_p1147_Caballero
work_keys_str_mv AT caballerogerardomanuel onthemechanismofcleavageofthioacetalspromotedbycopperiisulphateadsorbedonsilicagel
AT groseduardogervasio onthemechanismofcleavageofthioacetalspromotedbycopperiisulphateadsorbedonsilicagel
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