Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood
Activated carbons from invasive Parkinsonia aculeata wood sawdust were developed by microwave assisted H3PO4 acid activation varying the radiation time (2–10 min). Their main physicochemical characteristics were determined, and compared with those of a sample previously obtained by conventional heat...
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paper:paper_09295607_v22_n3_p347_Nunell2023-06-08T15:52:25Z Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood Nunell, Gisel Vanesa Fernández, María Emilia Bonelli, Pablo R. Cukierman, Ana Lea Activated carbon H3PO4 acid activation Microwave assistance Phenol adsorption Adsorption Chemical activation Heating Microwaves Phenols Acid activation Adsorption capacities Conventional heating Impregnation ratios Microwave energies Parkinsonia aculeata Phenol adsorption Physicochemical characteristics Activated carbon Activated carbons from invasive Parkinsonia aculeata wood sawdust were developed by microwave assisted H3PO4 acid activation varying the radiation time (2–10 min). Their main physicochemical characteristics were determined, and compared with those of a sample previously obtained by conventional heating using the same precursor, chemical agent, and impregnation ratio. The activated carbons developed for radiation times of 5 and 10 min showed higher BET surface areas (~1300 m2/g) and total pore volume (1 cm3/g) than those obtained at 2 min (~710 m2/g) or by conventional heating (~970 m2/g). Microwave assisted activation also led to activated carbons with higher total amounts of acidic oxygen and basic functionalities in comparison with the sample arising from conventional heating. Phenol adsorption capacity for all the samples was also evaluated from determination of the adsorption isotherms and their proper description by the Freundlich model. The adsorption capacity for the activated carbons obtained at 5 and 10 min was almost twice that measured for the samples prepared at 2 min and by conventional heating, in agreement with the higher BET surface areas characterizing the former. Compared with conventional heating, the process assistance by microwave energy not only reduced operation time, but also improved the characteristics of the resulting activated carbons. © 2016, Springer Science+Business Media New York. Fil:Nunell, G.V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fernandez, M.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bonelli, P.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cukierman, A.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2016 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09295607_v22_n3_p347_Nunell http://hdl.handle.net/20.500.12110/paper_09295607_v22_n3_p347_Nunell |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Activated carbon H3PO4 acid activation Microwave assistance Phenol adsorption Adsorption Chemical activation Heating Microwaves Phenols Acid activation Adsorption capacities Conventional heating Impregnation ratios Microwave energies Parkinsonia aculeata Phenol adsorption Physicochemical characteristics Activated carbon |
| spellingShingle |
Activated carbon H3PO4 acid activation Microwave assistance Phenol adsorption Adsorption Chemical activation Heating Microwaves Phenols Acid activation Adsorption capacities Conventional heating Impregnation ratios Microwave energies Parkinsonia aculeata Phenol adsorption Physicochemical characteristics Activated carbon Nunell, Gisel Vanesa Fernández, María Emilia Bonelli, Pablo R. Cukierman, Ana Lea Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood |
| topic_facet |
Activated carbon H3PO4 acid activation Microwave assistance Phenol adsorption Adsorption Chemical activation Heating Microwaves Phenols Acid activation Adsorption capacities Conventional heating Impregnation ratios Microwave energies Parkinsonia aculeata Phenol adsorption Physicochemical characteristics Activated carbon |
| description |
Activated carbons from invasive Parkinsonia aculeata wood sawdust were developed by microwave assisted H3PO4 acid activation varying the radiation time (2–10 min). Their main physicochemical characteristics were determined, and compared with those of a sample previously obtained by conventional heating using the same precursor, chemical agent, and impregnation ratio. The activated carbons developed for radiation times of 5 and 10 min showed higher BET surface areas (~1300 m2/g) and total pore volume (1 cm3/g) than those obtained at 2 min (~710 m2/g) or by conventional heating (~970 m2/g). Microwave assisted activation also led to activated carbons with higher total amounts of acidic oxygen and basic functionalities in comparison with the sample arising from conventional heating. Phenol adsorption capacity for all the samples was also evaluated from determination of the adsorption isotherms and their proper description by the Freundlich model. The adsorption capacity for the activated carbons obtained at 5 and 10 min was almost twice that measured for the samples prepared at 2 min and by conventional heating, in agreement with the higher BET surface areas characterizing the former. Compared with conventional heating, the process assistance by microwave energy not only reduced operation time, but also improved the characteristics of the resulting activated carbons. © 2016, Springer Science+Business Media New York. |
| author |
Nunell, Gisel Vanesa Fernández, María Emilia Bonelli, Pablo R. Cukierman, Ana Lea |
| author_facet |
Nunell, Gisel Vanesa Fernández, María Emilia Bonelli, Pablo R. Cukierman, Ana Lea |
| author_sort |
Nunell, Gisel Vanesa |
| title |
Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood |
| title_short |
Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood |
| title_full |
Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood |
| title_fullStr |
Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood |
| title_full_unstemmed |
Development and characterization of microwave-assisted activated carbons from Parkinsonea aculeata wood |
| title_sort |
development and characterization of microwave-assisted activated carbons from parkinsonea aculeata wood |
| publishDate |
2016 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09295607_v22_n3_p347_Nunell http://hdl.handle.net/20.500.12110/paper_09295607_v22_n3_p347_Nunell |
| work_keys_str_mv |
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| _version_ |
1768545150785552384 |