Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content

The Ni(II)Mg(II)Al(III) LDH were obtained by homogeneous precipitation urea method, after a proper thermal treatment resulted in an active catalyst for the ethanol steam reforming. After catalytic performance, catalysts were analyzed by temperature programmed oxidation (TPO), in order to quantify ca...

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Detalles Bibliográficos
Autores principales:	Jobbagy, Matias, Amadeo, Norma Elvira
Publicado:	2014
Materias:	Bioethanol Hydrogen production LDH Ni catalyst Reforming Characteristic signal Ethanol steam reforming Experimental equipments Homogeneous Precipitation Ni catalysts Temperature programmed oxidation Thermogravimetric studies Catalysts Equipment Ethanol Nickel Quartz Reforming reactions Thermocouples Urea Steam reforming
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0926860X_v470_n_p398_Romero http://hdl.handle.net/20.500.12110/paper_0926860X_v470_n_p398_Romero
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_0926860X_v470_n_p398_Romero
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spelling	paper:paper_0926860X_v470_n_p398_Romero2023-06-08T15:51:42Z Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content Jobbagy, Matias Amadeo, Norma Elvira Bioethanol Hydrogen production LDH Ni catalyst Reforming Characteristic signal Ethanol steam reforming Experimental equipments Homogeneous Precipitation LDH Ni catalysts Temperature programmed oxidation Thermogravimetric studies Bioethanol Catalysts Equipment Ethanol Hydrogen production Nickel Quartz Reforming reactions Thermocouples Urea Steam reforming The Ni(II)Mg(II)Al(III) LDH were obtained by homogeneous precipitation urea method, after a proper thermal treatment resulted in an active catalyst for the ethanol steam reforming. After catalytic performance, catalysts were analyzed by temperature programmed oxidation (TPO), in order to quantify carbon deposits. Reduced Ni area was evaluated by H2 static volumetric chemisorption measurements in a Micromeritics AutoChem II 2920 equipment. Thermogravimetric studies were carried out in a Shimadzu TGA-51H equipment, using a heating ramp of 10 K/min in air flow of 50 cm3/min. Experimental equipment used for catalytic evaluation consists of a quartz tubular reactor heated in electric oven at the reaction temperature, which is monitored by a thermocouple placed inside the reactor. The vaporized current is diluted with argon at the entrance of the reactor. It can be observed PXRD spectra of precursors with different Mg content, all samples show characteristic signals of LDH. Fil:Jobbágy, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Amadeo, N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2014 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0926860X_v470_n_p398_Romero http://hdl.handle.net/20.500.12110/paper_0926860X_v470_n_p398_Romero
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Bioethanol Hydrogen production LDH Ni catalyst Reforming Characteristic signal Ethanol steam reforming Experimental equipments Homogeneous Precipitation LDH Ni catalysts Temperature programmed oxidation Thermogravimetric studies Bioethanol Catalysts Equipment Ethanol Hydrogen production Nickel Quartz Reforming reactions Thermocouples Urea Steam reforming
spellingShingle	Bioethanol Hydrogen production LDH Ni catalyst Reforming Characteristic signal Ethanol steam reforming Experimental equipments Homogeneous Precipitation LDH Ni catalysts Temperature programmed oxidation Thermogravimetric studies Bioethanol Catalysts Equipment Ethanol Hydrogen production Nickel Quartz Reforming reactions Thermocouples Urea Steam reforming Jobbagy, Matias Amadeo, Norma Elvira Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content
topic_facet	Bioethanol Hydrogen production LDH Ni catalyst Reforming Characteristic signal Ethanol steam reforming Experimental equipments Homogeneous Precipitation LDH Ni catalysts Temperature programmed oxidation Thermogravimetric studies Bioethanol Catalysts Equipment Ethanol Hydrogen production Nickel Quartz Reforming reactions Thermocouples Urea Steam reforming
description	The Ni(II)Mg(II)Al(III) LDH were obtained by homogeneous precipitation urea method, after a proper thermal treatment resulted in an active catalyst for the ethanol steam reforming. After catalytic performance, catalysts were analyzed by temperature programmed oxidation (TPO), in order to quantify carbon deposits. Reduced Ni area was evaluated by H2 static volumetric chemisorption measurements in a Micromeritics AutoChem II 2920 equipment. Thermogravimetric studies were carried out in a Shimadzu TGA-51H equipment, using a heating ramp of 10 K/min in air flow of 50 cm3/min. Experimental equipment used for catalytic evaluation consists of a quartz tubular reactor heated in electric oven at the reaction temperature, which is monitored by a thermocouple placed inside the reactor. The vaporized current is diluted with argon at the entrance of the reactor. It can be observed PXRD spectra of precursors with different Mg content, all samples show characteristic signals of LDH.
author	Jobbagy, Matias Amadeo, Norma Elvira
author_facet	Jobbagy, Matias Amadeo, Norma Elvira
author_sort	Jobbagy, Matias
title	Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content
title_short	Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content
title_full	Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content
title_fullStr	Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content
title_full_unstemmed	Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content
title_sort	ni(ii)-mg(ii)-al(iii) catalysts for hydrogen production from ethanol steam reforming: influence of the mg content
publishDate	2014
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0926860X_v470_n_p398_Romero http://hdl.handle.net/20.500.12110/paper_0926860X_v470_n_p398_Romero
work_keys_str_mv	AT jobbagymatias niiimgiialiiicatalystsforhydrogenproductionfromethanolsteamreforminginfluenceofthemgcontent AT amadeonormaelvira niiimgiialiiicatalystsforhydrogenproductionfromethanolsteamreforminginfluenceofthemgcontent
_version_	1768544419063005184

Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the Mg content

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