Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye

A novel photoaddressable copolymer with low glass transition temperature was synthesised and its optical properties were studied. The photoresponsive material was obtained from chemical modification of a poly(styrene-co-acrylic acid) copolymer. A holographic polarization grating was recorded in the...

Descripción completa

Detalles Bibliográficos
Autores principales: D'Accorso, Norma Beatriz, Ledesma, Silvia Adriana, Goyanes, Silvia Nair
Publicado: 2015
Materias:
Azobenzene
Azopolymer
Copolymer
Diffraction gratings
Azo dyes
Chemical modification
Copolymers
Diffraction
Glass
Holographic gratings
Holography
Nanocomposites
Optical properties
Styrene
Temperature
Low glass transition temperatures
Near room temperature
Photo-responsive
Polarization gratings
Poly(styreneco-acrylic acid)
Polymer glass transition
Statistical copolymers
Glass transition
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09253467_v49_n_p141_Cambiasso
http://hdl.handle.net/20.500.12110/paper_09253467_v49_n_p141_Cambiasso
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_09253467_v49_n_p141_Cambiasso
record_format dspace
spelling paper:paper_09253467_v49_n_p141_Cambiasso2023-06-08T15:51:13Z Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye D'Accorso, Norma Beatriz Ledesma, Silvia Adriana Goyanes, Silvia Nair Azobenzene Azopolymer Copolymer Diffraction gratings Azo dyes Azobenzene Chemical modification Copolymers Diffraction Diffraction gratings Glass Holographic gratings Holography Nanocomposites Optical properties Styrene Temperature Azopolymer Low glass transition temperatures Near room temperature Photo-responsive Polarization gratings Poly(styreneco-acrylic acid) Polymer glass transition Statistical copolymers Glass transition A novel photoaddressable copolymer with low glass transition temperature was synthesised and its optical properties were studied. The photoresponsive material was obtained from chemical modification of a poly(styrene-co-acrylic acid) copolymer. A holographic polarization grating was recorded in the material and was monitored by measuring its diffraction efficiency. It is shown that the holographic grating stored in the material is highly stable in time, despite the fact that the polymer glass transition temperature is near room temperature. This stability is a consequence of electrostatic interactions between the azo-groups and the carboxylic substituent group of the main polymer chain. © 2015 Elsevier B.V. All rights reserved. Fil:D'Accorso, N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Ledesma, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Goyanes, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2015 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09253467_v49_n_p141_Cambiasso http://hdl.handle.net/20.500.12110/paper_09253467_v49_n_p141_Cambiasso
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Azobenzene
Azopolymer
Copolymer
Diffraction gratings
Azo dyes
Azobenzene
Chemical modification
Copolymers
Diffraction
Diffraction gratings
Glass
Holographic gratings
Holography
Nanocomposites
Optical properties
Styrene
Temperature
Azopolymer
Low glass transition temperatures
Near room temperature
Photo-responsive
Polarization gratings
Poly(styreneco-acrylic acid)
Polymer glass transition
Statistical copolymers
Glass transition
spellingShingle Azobenzene
Azopolymer
Copolymer
Diffraction gratings
Azo dyes
Azobenzene
Chemical modification
Copolymers
Diffraction
Diffraction gratings
Glass
Holographic gratings
Holography
Nanocomposites
Optical properties
Styrene
Temperature
Azopolymer
Low glass transition temperatures
Near room temperature
Photo-responsive
Polarization gratings
Poly(styreneco-acrylic acid)
Polymer glass transition
Statistical copolymers
Glass transition
D'Accorso, Norma Beatriz
Ledesma, Silvia Adriana
Goyanes, Silvia Nair
Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye
topic_facet Azobenzene
Azopolymer
Copolymer
Diffraction gratings
Azo dyes
Azobenzene
Chemical modification
Copolymers
Diffraction
Diffraction gratings
Glass
Holographic gratings
Holography
Nanocomposites
Optical properties
Styrene
Temperature
Azopolymer
Low glass transition temperatures
Near room temperature
Photo-responsive
Polarization gratings
Poly(styreneco-acrylic acid)
Polymer glass transition
Statistical copolymers
Glass transition
description A novel photoaddressable copolymer with low glass transition temperature was synthesised and its optical properties were studied. The photoresponsive material was obtained from chemical modification of a poly(styrene-co-acrylic acid) copolymer. A holographic polarization grating was recorded in the material and was monitored by measuring its diffraction efficiency. It is shown that the holographic grating stored in the material is highly stable in time, despite the fact that the polymer glass transition temperature is near room temperature. This stability is a consequence of electrostatic interactions between the azo-groups and the carboxylic substituent group of the main polymer chain. © 2015 Elsevier B.V. All rights reserved.
author D'Accorso, Norma Beatriz
Ledesma, Silvia Adriana
Goyanes, Silvia Nair
author_facet D'Accorso, Norma Beatriz
Ledesma, Silvia Adriana
Goyanes, Silvia Nair
author_sort D'Accorso, Norma Beatriz
title Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye
title_short Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye
title_full Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye
title_fullStr Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye
title_full_unstemmed Optical recording of stable holographic grating in a low Tg statistical copolymer covalently functionalized with an azo-dye
title_sort optical recording of stable holographic grating in a low tg statistical copolymer covalently functionalized with an azo-dye
publishDate 2015
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09253467_v49_n_p141_Cambiasso
http://hdl.handle.net/20.500.12110/paper_09253467_v49_n_p141_Cambiasso
work_keys_str_mv AT daccorsonormabeatriz opticalrecordingofstableholographicgratinginalowtgstatisticalcopolymercovalentlyfunctionalizedwithanazodye
AT ledesmasilviaadriana opticalrecordingofstableholographicgratinginalowtgstatisticalcopolymercovalentlyfunctionalizedwithanazodye
AT goyanessilvianair opticalrecordingofstableholographicgratinginalowtgstatisticalcopolymercovalentlyfunctionalizedwithanazodye
_version_ 1768544281728909312

Ejemplares similares