A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity
A new oxido-vanadium(V) complex, [VO(L)(PrOH)(OPr)] (L = [(3-methoxy-2oxidobenzylidene)benzohydrazidato], PrOH = propanol, OPr = propanolato) has been synthesized and characterized by means of elemental analysis, Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1HNMR), ultaviole...
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paper:paper_09226168_v42_n2_p611_Ebrahimipour2023-06-08T15:50:53Z A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity Suarez, Sebastian Anti-microbial activity Biofilm formation Electrochemical behavior Schiff base ligand V(V) complex Bacillus cereus Bacteria Bacteriology Bioactivity Complexation Crystal atomic structure Escherichia coli Fourier transform infrared spectroscopy Functional groups Ligands Nuclear magnetic resonance spectroscopy Propanol Single crystals Spectrum analyzers Vanadium compounds X ray diffraction Anti-microbial activity Biofilm formation Electrochemical behaviors Electrochemical evaluations Fourier transform infrared Proton nuclear magnetic resonance Schiff-base ligands Single crystal x-ray diffraction Crystal structure A new oxido-vanadium(V) complex, [VO(L)(PrOH)(OPr)] (L = [(3-methoxy-2oxidobenzylidene)benzohydrazidato], PrOH = propanol, OPr = propanolato) has been synthesized and characterized by means of elemental analysis, Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1HNMR), ultaviolet-visible (UV-Vis) spectroscopy, voltammetry and molar conductivity measurement. The structure of the complex has also determined using single crystal X-ray diffraction. The geometric structure around the V(V) ion has been found to be octahedral in which the positions around the central ion are occupied by ONO ligand donors, oxido groups, and oxygen atoms of coordinated propanol and propoxide group. Electrochemical behavior of this complex is also discussed in more details. In vitro antimicrobial effect of the title complex has investigated exhibiting significant activities against some Gram-positive (Staphylococcus aureus, Micrococcus luteus, Bacillus cereus, Eterococcus faecalis) and Gram-negative bacteria (Pseudomonas aeruginosa, Escherichia coli, Klebsiella sp, Pseudomonas sp) and fungus strain (Candida albicans). © 2015 Springer Science+Business Media Dordrecht. Fil:Suárez, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2016 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09226168_v42_n2_p611_Ebrahimipour http://hdl.handle.net/20.500.12110/paper_09226168_v42_n2_p611_Ebrahimipour |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Anti-microbial activity Biofilm formation Electrochemical behavior Schiff base ligand V(V) complex Bacillus cereus Bacteria Bacteriology Bioactivity Complexation Crystal atomic structure Escherichia coli Fourier transform infrared spectroscopy Functional groups Ligands Nuclear magnetic resonance spectroscopy Propanol Single crystals Spectrum analyzers Vanadium compounds X ray diffraction Anti-microbial activity Biofilm formation Electrochemical behaviors Electrochemical evaluations Fourier transform infrared Proton nuclear magnetic resonance Schiff-base ligands Single crystal x-ray diffraction Crystal structure |
| spellingShingle |
Anti-microbial activity Biofilm formation Electrochemical behavior Schiff base ligand V(V) complex Bacillus cereus Bacteria Bacteriology Bioactivity Complexation Crystal atomic structure Escherichia coli Fourier transform infrared spectroscopy Functional groups Ligands Nuclear magnetic resonance spectroscopy Propanol Single crystals Spectrum analyzers Vanadium compounds X ray diffraction Anti-microbial activity Biofilm formation Electrochemical behaviors Electrochemical evaluations Fourier transform infrared Proton nuclear magnetic resonance Schiff-base ligands Single crystal x-ray diffraction Crystal structure Suarez, Sebastian A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity |
| topic_facet |
Anti-microbial activity Biofilm formation Electrochemical behavior Schiff base ligand V(V) complex Bacillus cereus Bacteria Bacteriology Bioactivity Complexation Crystal atomic structure Escherichia coli Fourier transform infrared spectroscopy Functional groups Ligands Nuclear magnetic resonance spectroscopy Propanol Single crystals Spectrum analyzers Vanadium compounds X ray diffraction Anti-microbial activity Biofilm formation Electrochemical behaviors Electrochemical evaluations Fourier transform infrared Proton nuclear magnetic resonance Schiff-base ligands Single crystal x-ray diffraction Crystal structure |
| description |
A new oxido-vanadium(V) complex, [VO(L)(PrOH)(OPr)] (L = [(3-methoxy-2oxidobenzylidene)benzohydrazidato], PrOH = propanol, OPr = propanolato) has been synthesized and characterized by means of elemental analysis, Fourier transform infrared (FTIR), proton nuclear magnetic resonance (1HNMR), ultaviolet-visible (UV-Vis) spectroscopy, voltammetry and molar conductivity measurement. The structure of the complex has also determined using single crystal X-ray diffraction. The geometric structure around the V(V) ion has been found to be octahedral in which the positions around the central ion are occupied by ONO ligand donors, oxido groups, and oxygen atoms of coordinated propanol and propoxide group. Electrochemical behavior of this complex is also discussed in more details. In vitro antimicrobial effect of the title complex has investigated exhibiting significant activities against some Gram-positive (Staphylococcus aureus, Micrococcus luteus, Bacillus cereus, Eterococcus faecalis) and Gram-negative bacteria (Pseudomonas aeruginosa, Escherichia coli, Klebsiella sp, Pseudomonas sp) and fungus strain (Candida albicans). © 2015 Springer Science+Business Media Dordrecht. |
| author |
Suarez, Sebastian |
| author_facet |
Suarez, Sebastian |
| author_sort |
Suarez, Sebastian |
| title |
A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity |
| title_short |
A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity |
| title_full |
A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity |
| title_fullStr |
A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity |
| title_full_unstemmed |
A novel oxido-vanadium(V) Schiff base complex: Synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity |
| title_sort |
novel oxido-vanadium(v) schiff base complex: synthesis, spectral characterization, crystal structure, electrochemical evaluation, and biological activity |
| publishDate |
2016 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09226168_v42_n2_p611_Ebrahimipour http://hdl.handle.net/20.500.12110/paper_09226168_v42_n2_p611_Ebrahimipour |
| work_keys_str_mv |
AT suarezsebastian anoveloxidovanadiumvschiffbasecomplexsynthesisspectralcharacterizationcrystalstructureelectrochemicalevaluationandbiologicalactivity AT suarezsebastian noveloxidovanadiumvschiffbasecomplexsynthesisspectralcharacterizationcrystalstructureelectrochemicalevaluationandbiologicalactivity |
| _version_ |
1768543188024295424 |