Anisotropy and relaxation processes of uniaxially oriented CoFe 2O 4 nanoparticles dispersed in PDMS
When a uniaxial magnetic field is applied to a non-magnetic dispersive medium filled with magnetic nanoparticles, they auto-assemble into thin needles parallel to the field direction, due to the strong dipolar interaction among them. We have prepared in this way magnetically oriented nanocomposites...
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v407_n16_p3165_Antonel http://hdl.handle.net/20.500.12110/paper_09214526_v407_n16_p3165_Antonel |
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paper:paper_09214526_v407_n16_p3165_Antonel2023-06-08T15:50:37Z Anisotropy and relaxation processes of uniaxially oriented CoFe 2O 4 nanoparticles dispersed in PDMS Antonel, Paula Soledad Negri, Ricardo Martin Jorge, Guillermo Antonio Magnetic anisotropy Magnetic viscosity Magnetoelastomers Relaxation Dipolar interaction Dispersive medium Field directions Local magnetic anisotropy Logarithmic relaxation Magnetic nanoparticles Magnetic particle Magnetic viscosity Magnetoelastomers Nanometer size Nonmagnetics Polydimethylsiloxane polymers Relaxation Magnetic anisotropy Magnetic fields Needles Relaxation processes Silicones Nanoparticles When a uniaxial magnetic field is applied to a non-magnetic dispersive medium filled with magnetic nanoparticles, they auto-assemble into thin needles parallel to the field direction, due to the strong dipolar interaction among them. We have prepared in this way magnetically oriented nanocomposites of nanometer-size CoFe 2O 4 particles in a polydimethylsiloxane polymer matrix, with 10% w/w of magnetic particles. We present the characteristic magnetic relaxation curves measured after the application of a magnetic field forming an angle α with respect to the needle direction. We show that the magnetic viscosity (calculated from the logarithmic relaxation curves) as a function of α presents a minimum at α=0, indicating slower relaxation processes associated with this configuration of fields. The results seems to point out that the local magnetic anisotropy of the nanoparticles is oriented along the needles, resulting in the macroscopic magnetic anisotropy observed in our measurements. © 2011 Elsevier B.V. All rights reserved. Fil:Antonel, P.S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Negri, R.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Jorge, G.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2012 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v407_n16_p3165_Antonel http://hdl.handle.net/20.500.12110/paper_09214526_v407_n16_p3165_Antonel |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Magnetic anisotropy Magnetic viscosity Magnetoelastomers Relaxation Dipolar interaction Dispersive medium Field directions Local magnetic anisotropy Logarithmic relaxation Magnetic nanoparticles Magnetic particle Magnetic viscosity Magnetoelastomers Nanometer size Nonmagnetics Polydimethylsiloxane polymers Relaxation Magnetic anisotropy Magnetic fields Needles Relaxation processes Silicones Nanoparticles |
spellingShingle |
Magnetic anisotropy Magnetic viscosity Magnetoelastomers Relaxation Dipolar interaction Dispersive medium Field directions Local magnetic anisotropy Logarithmic relaxation Magnetic nanoparticles Magnetic particle Magnetic viscosity Magnetoelastomers Nanometer size Nonmagnetics Polydimethylsiloxane polymers Relaxation Magnetic anisotropy Magnetic fields Needles Relaxation processes Silicones Nanoparticles Antonel, Paula Soledad Negri, Ricardo Martin Jorge, Guillermo Antonio Anisotropy and relaxation processes of uniaxially oriented CoFe 2O 4 nanoparticles dispersed in PDMS |
topic_facet |
Magnetic anisotropy Magnetic viscosity Magnetoelastomers Relaxation Dipolar interaction Dispersive medium Field directions Local magnetic anisotropy Logarithmic relaxation Magnetic nanoparticles Magnetic particle Magnetic viscosity Magnetoelastomers Nanometer size Nonmagnetics Polydimethylsiloxane polymers Relaxation Magnetic anisotropy Magnetic fields Needles Relaxation processes Silicones Nanoparticles |
description |
When a uniaxial magnetic field is applied to a non-magnetic dispersive medium filled with magnetic nanoparticles, they auto-assemble into thin needles parallel to the field direction, due to the strong dipolar interaction among them. We have prepared in this way magnetically oriented nanocomposites of nanometer-size CoFe 2O 4 particles in a polydimethylsiloxane polymer matrix, with 10% w/w of magnetic particles. We present the characteristic magnetic relaxation curves measured after the application of a magnetic field forming an angle α with respect to the needle direction. We show that the magnetic viscosity (calculated from the logarithmic relaxation curves) as a function of α presents a minimum at α=0, indicating slower relaxation processes associated with this configuration of fields. The results seems to point out that the local magnetic anisotropy of the nanoparticles is oriented along the needles, resulting in the macroscopic magnetic anisotropy observed in our measurements. © 2011 Elsevier B.V. All rights reserved. |
author |
Antonel, Paula Soledad Negri, Ricardo Martin Jorge, Guillermo Antonio |
author_facet |
Antonel, Paula Soledad Negri, Ricardo Martin Jorge, Guillermo Antonio |
author_sort |
Antonel, Paula Soledad |
title |
Anisotropy and relaxation processes of uniaxially oriented CoFe 2O 4 nanoparticles dispersed in PDMS |
title_short |
Anisotropy and relaxation processes of uniaxially oriented CoFe 2O 4 nanoparticles dispersed in PDMS |
title_full |
Anisotropy and relaxation processes of uniaxially oriented CoFe 2O 4 nanoparticles dispersed in PDMS |
title_fullStr |
Anisotropy and relaxation processes of uniaxially oriented CoFe 2O 4 nanoparticles dispersed in PDMS |
title_full_unstemmed |
Anisotropy and relaxation processes of uniaxially oriented CoFe 2O 4 nanoparticles dispersed in PDMS |
title_sort |
anisotropy and relaxation processes of uniaxially oriented cofe 2o 4 nanoparticles dispersed in pdms |
publishDate |
2012 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v407_n16_p3165_Antonel http://hdl.handle.net/20.500.12110/paper_09214526_v407_n16_p3165_Antonel |
work_keys_str_mv |
AT antonelpaulasoledad anisotropyandrelaxationprocessesofuniaxiallyorientedcofe2o4nanoparticlesdispersedinpdms AT negriricardomartin anisotropyandrelaxationprocessesofuniaxiallyorientedcofe2o4nanoparticlesdispersedinpdms AT jorgeguillermoantonio anisotropyandrelaxationprocessesofuniaxiallyorientedcofe2o4nanoparticlesdispersedinpdms |
_version_ |
1768546682142720000 |