Solubility of crystalline alkali metal iodides in supercritical ammonia

The solubilities of crystalline NaI, KI and CsI in supercritical ammonia (SCA) were determined for temperatures around 420 K and different ammonia densities smaller than the critical density using the spectral charge-transfer-to-solvent (ctts) band of iodides. The optical absorptivity of the ctts ba...

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Autores principales:	Sciaini, Alberto Germán, Marceca, Ernesto Jose, Fernandez Prini, Roberto
Publicado:	2005
Materias:	Alkali metal iodide Charge-transfer-to-solvent Solubility Solvation Supercritical ammonia Ammonia Charge transfer Light absorption Precipitation (chemical) Solutions Ultraviolet radiation Alkali metals
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08968446_v35_n2_p106_Sciaini http://hdl.handle.net/20.500.12110/paper_08968446_v35_n2_p106_Sciaini
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_08968446_v35_n2_p106_Sciaini
record_format	dspace
spelling	paper:paper_08968446_v35_n2_p106_Sciaini2023-06-08T15:49:14Z Solubility of crystalline alkali metal iodides in supercritical ammonia Sciaini, Alberto Germán Marceca, Ernesto Jose Fernandez Prini, Roberto Alkali metal iodide Charge-transfer-to-solvent Solubility Solvation Supercritical ammonia Ammonia Charge transfer Light absorption Precipitation (chemical) Solubility Solutions Ultraviolet radiation Alkali metal iodide Charge-transfer-to-solvent Solvation Supercritical ammonia Alkali metals The solubilities of crystalline NaI, KI and CsI in supercritical ammonia (SCA) were determined for temperatures around 420 K and different ammonia densities smaller than the critical density using the spectral charge-transfer-to-solvent (ctts) band of iodides. The optical absorptivity of the ctts band was also determined with the potassium salt and shown to be density independent. The results show that the solubility of the alkali metal iodides exhibit a very simple dependence on fluid density; this implies that over the density range we have explored, the first solvation shell of the ion pairs is mostly complete even at the lowest studied density. © 2005 Elsevier B.V. All rights reserved. Fil:Sciaini, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Marceca, E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fernández-Prini, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2005 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08968446_v35_n2_p106_Sciaini http://hdl.handle.net/20.500.12110/paper_08968446_v35_n2_p106_Sciaini
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Alkali metal iodide Charge-transfer-to-solvent Solubility Solvation Supercritical ammonia Ammonia Charge transfer Light absorption Precipitation (chemical) Solubility Solutions Ultraviolet radiation Alkali metal iodide Charge-transfer-to-solvent Solvation Supercritical ammonia Alkali metals
spellingShingle	Alkali metal iodide Charge-transfer-to-solvent Solubility Solvation Supercritical ammonia Ammonia Charge transfer Light absorption Precipitation (chemical) Solubility Solutions Ultraviolet radiation Alkali metal iodide Charge-transfer-to-solvent Solvation Supercritical ammonia Alkali metals Sciaini, Alberto Germán Marceca, Ernesto Jose Fernandez Prini, Roberto Solubility of crystalline alkali metal iodides in supercritical ammonia
topic_facet	Alkali metal iodide Charge-transfer-to-solvent Solubility Solvation Supercritical ammonia Ammonia Charge transfer Light absorption Precipitation (chemical) Solubility Solutions Ultraviolet radiation Alkali metal iodide Charge-transfer-to-solvent Solvation Supercritical ammonia Alkali metals
description	The solubilities of crystalline NaI, KI and CsI in supercritical ammonia (SCA) were determined for temperatures around 420 K and different ammonia densities smaller than the critical density using the spectral charge-transfer-to-solvent (ctts) band of iodides. The optical absorptivity of the ctts band was also determined with the potassium salt and shown to be density independent. The results show that the solubility of the alkali metal iodides exhibit a very simple dependence on fluid density; this implies that over the density range we have explored, the first solvation shell of the ion pairs is mostly complete even at the lowest studied density. © 2005 Elsevier B.V. All rights reserved.
author	Sciaini, Alberto Germán Marceca, Ernesto Jose Fernandez Prini, Roberto
author_facet	Sciaini, Alberto Germán Marceca, Ernesto Jose Fernandez Prini, Roberto
author_sort	Sciaini, Alberto Germán
title	Solubility of crystalline alkali metal iodides in supercritical ammonia
title_short	Solubility of crystalline alkali metal iodides in supercritical ammonia
title_full	Solubility of crystalline alkali metal iodides in supercritical ammonia
title_fullStr	Solubility of crystalline alkali metal iodides in supercritical ammonia
title_full_unstemmed	Solubility of crystalline alkali metal iodides in supercritical ammonia
title_sort	solubility of crystalline alkali metal iodides in supercritical ammonia
publishDate	2005
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08968446_v35_n2_p106_Sciaini http://hdl.handle.net/20.500.12110/paper_08968446_v35_n2_p106_Sciaini
work_keys_str_mv	AT sciainialbertogerman solubilityofcrystallinealkalimetaliodidesinsupercriticalammonia AT marcecaernestojose solubilityofcrystallinealkalimetaliodidesinsupercriticalammonia AT fernandezpriniroberto solubilityofcrystallinealkalimetaliodidesinsupercriticalammonia
_version_	1768545981032300544

Solubility of crystalline alkali metal iodides in supercritical ammonia

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