Intramolecular carbolithiation-cyclization-electrophilic substitution: Solvent effect and mechanistic study

The intramolecular carbolithiation-cyclization-electrophilic substitution sequence proves to be a promising strategy for synthetic organic chemists. Our current research in this area focuses on the one-pot halogen/lithium exchange of 2-bromophenyl-3-phenylprop-2-enyl ether, followed by intramolecula...

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Detalles Bibliográficos
Publicado:	2014
Materias:	carbolithiation-cyclization-electrophilic substitution conducted tour mechanism inversion mechanism SE2 electrophilic substitution solvent effect Cyclization Reaction intermediates Stereoselectivity 2 ,3-dihydrobenzofurans Diastereo-selectivity Electrophilic substitutions Intramolecular carbolithiation Inversion of configuration Product distributions Solvent effects Theoretical calculations Solvents
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08943230_v34_n4_p322_Rodriguez http://hdl.handle.net/20.500.12110/paper_08943230_v34_n4_p322_Rodriguez
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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