Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines

The synthesis and spectroscopic properties (1H, 13C and 15N NMR, in solution and in the solid state) of six new 1-adamantylmethlene azines are reported. The crystal and molecular structures of 1-adamantylcarbaldehyde azine and 1-adamantyl methyl ketone azine, which exist in the solid state in the E,...

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Detalles Bibliográficos
Autor principal: Ponce, María Alejandra
Publicado: 1999
Materias:
ab initio calculations
Adamantylmethyleneazines
Cross-polarization magic angle spinning NMR
Multinuclear magnetic resonance
X-ray structures
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08943230_v12_n6_p455_Sanz
http://hdl.handle.net/20.500.12110/paper_08943230_v12_n6_p455_Sanz
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_08943230_v12_n6_p455_Sanz
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spelling paper:paper_08943230_v12_n6_p455_Sanz2023-06-08T15:47:42Z Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines Ponce, María Alejandra ab initio calculations Adamantylmethyleneazines Cross-polarization magic angle spinning NMR Multinuclear magnetic resonance X-ray structures The synthesis and spectroscopic properties (1H, 13C and 15N NMR, in solution and in the solid state) of six new 1-adamantylmethlene azines are reported. The crystal and molecular structures of 1-adamantylcarbaldehyde azine and 1-adamantyl methyl ketone azine, which exist in the solid state in the E,E-configuration, were determined by x-ray analysis. The geometric characteristics of the azine central bridge and the preferred configuration with regard to it (E,E, E,Z, or Z,Z) were investigated by means of the crystallographic data retrieved from the Cambridge Structural Database and ab initio quantum chemical calculations. Copyright © 1999 John Wiley & Sons, Ltd. Fil:Ponce, M.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1999 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08943230_v12_n6_p455_Sanz http://hdl.handle.net/20.500.12110/paper_08943230_v12_n6_p455_Sanz
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic ab initio calculations
Adamantylmethyleneazines
Cross-polarization magic angle spinning NMR
Multinuclear magnetic resonance
X-ray structures
spellingShingle ab initio calculations
Adamantylmethyleneazines
Cross-polarization magic angle spinning NMR
Multinuclear magnetic resonance
X-ray structures
Ponce, María Alejandra
Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines
topic_facet ab initio calculations
Adamantylmethyleneazines
Cross-polarization magic angle spinning NMR
Multinuclear magnetic resonance
X-ray structures
description The synthesis and spectroscopic properties (1H, 13C and 15N NMR, in solution and in the solid state) of six new 1-adamantylmethlene azines are reported. The crystal and molecular structures of 1-adamantylcarbaldehyde azine and 1-adamantyl methyl ketone azine, which exist in the solid state in the E,E-configuration, were determined by x-ray analysis. The geometric characteristics of the azine central bridge and the preferred configuration with regard to it (E,E, E,Z, or Z,Z) were investigated by means of the crystallographic data retrieved from the Cambridge Structural Database and ab initio quantum chemical calculations. Copyright © 1999 John Wiley & Sons, Ltd.
author Ponce, María Alejandra
author_facet Ponce, María Alejandra
author_sort Ponce, María Alejandra
title Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines
title_short Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines
title_full Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines
title_fullStr Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines
title_full_unstemmed Synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines
title_sort synthesis and structural studies of symmetric and unsymmetric adamantylmethyleneazines
publishDate 1999
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08943230_v12_n6_p455_Sanz
http://hdl.handle.net/20.500.12110/paper_08943230_v12_n6_p455_Sanz
work_keys_str_mv AT poncemariaalejandra synthesisandstructuralstudiesofsymmetricandunsymmetricadamantylmethyleneazines
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