Coverage and aggregation of gold nanoparticles on silanized glasses
We study the dynamics of the coverage and aggregation of gold nanoparticles over organosilanized glass substrates for different sizes of nanoparticles. We present measurements of extinction spectra and nanoparticle counting statistics and demonstrate that both methods are equivalent describing those...
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2010
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paper:paper_07437463_v26_n20_p15948_Scarpettini2023-06-08T15:44:58Z Coverage and aggregation of gold nanoparticles on silanized glasses Scarpettini, Alberto F. Bragas, Andrea Verónica Characteristic time Counting statistics Different sizes Electrostatic repulsion Extinction spectra Glass substrates Gold Nanoparticles Saturation values Exponential functions Glass Oligomers Substrates Nanoparticles We study the dynamics of the coverage and aggregation of gold nanoparticles over organosilanized glass substrates for different sizes of nanoparticles. We present measurements of extinction spectra and nanoparticle counting statistics and demonstrate that both methods are equivalent describing those processes. We introduce models that describe the mentioned dynamics, which are characterized by an exponential-like function with two relevant parameters: a saturation value and a characteristic time. The electrostatic repulsion plays a significant role in both processes. The aggregation is dominated by the mobility of the isolated nanoparticles, which first join in dimers and, further in time, in clusters of higher number of nanoparticles. © 2010 American Chemical Society. Fil:Scarpettini, A.F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bragas, A.V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2010 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v26_n20_p15948_Scarpettini http://hdl.handle.net/20.500.12110/paper_07437463_v26_n20_p15948_Scarpettini |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Characteristic time Counting statistics Different sizes Electrostatic repulsion Extinction spectra Glass substrates Gold Nanoparticles Saturation values Exponential functions Glass Oligomers Substrates Nanoparticles |
spellingShingle |
Characteristic time Counting statistics Different sizes Electrostatic repulsion Extinction spectra Glass substrates Gold Nanoparticles Saturation values Exponential functions Glass Oligomers Substrates Nanoparticles Scarpettini, Alberto F. Bragas, Andrea Verónica Coverage and aggregation of gold nanoparticles on silanized glasses |
topic_facet |
Characteristic time Counting statistics Different sizes Electrostatic repulsion Extinction spectra Glass substrates Gold Nanoparticles Saturation values Exponential functions Glass Oligomers Substrates Nanoparticles |
description |
We study the dynamics of the coverage and aggregation of gold nanoparticles over organosilanized glass substrates for different sizes of nanoparticles. We present measurements of extinction spectra and nanoparticle counting statistics and demonstrate that both methods are equivalent describing those processes. We introduce models that describe the mentioned dynamics, which are characterized by an exponential-like function with two relevant parameters: a saturation value and a characteristic time. The electrostatic repulsion plays a significant role in both processes. The aggregation is dominated by the mobility of the isolated nanoparticles, which first join in dimers and, further in time, in clusters of higher number of nanoparticles. © 2010 American Chemical Society. |
author |
Scarpettini, Alberto F. Bragas, Andrea Verónica |
author_facet |
Scarpettini, Alberto F. Bragas, Andrea Verónica |
author_sort |
Scarpettini, Alberto F. |
title |
Coverage and aggregation of gold nanoparticles on silanized glasses |
title_short |
Coverage and aggregation of gold nanoparticles on silanized glasses |
title_full |
Coverage and aggregation of gold nanoparticles on silanized glasses |
title_fullStr |
Coverage and aggregation of gold nanoparticles on silanized glasses |
title_full_unstemmed |
Coverage and aggregation of gold nanoparticles on silanized glasses |
title_sort |
coverage and aggregation of gold nanoparticles on silanized glasses |
publishDate |
2010 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v26_n20_p15948_Scarpettini http://hdl.handle.net/20.500.12110/paper_07437463_v26_n20_p15948_Scarpettini |
work_keys_str_mv |
AT scarpettinialbertof coverageandaggregationofgoldnanoparticlesonsilanizedglasses AT bragasandreaveronica coverageandaggregationofgoldnanoparticlesonsilanizedglasses |
_version_ |
1768546449481531392 |