Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica

Stimuli-responsive polymers are used in a large variety of applications due to the controlled manner in which their physical properties can be reversibly altered. In this study, we demonstrate the thermoreversible structuring of poly-(N-isopropylacrylamide)-based polymer. By temperature-controlled a...

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Autor principal: Jares, Elizabeth Andrea
Publicado: 2006
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v22_n23_p9682_Pelah
http://hdl.handle.net/20.500.12110/paper_07437463_v22_n23_p9682_Pelah
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spelling paper:paper_07437463_v22_n23_p9682_Pelah2023-06-08T15:44:54Z Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica Jares, Elizabeth Andrea Critical solution temperature Heating cycles Polymer aggregates Stimuli-responsive polymers Agglomeration Atomic force microscopy Functional polymers Heating Mica Nanostructured materials acrylamide derivative aluminum silicate mica nanomaterial poly(n isopropylacrylamide) poly(N-isopropylacrylamide) polymer article atomic force microscopy chemistry surface property temperature ultrastructure Acrylamides Aluminum Silicates Microscopy, Atomic Force Nanostructures Polymers Surface Properties Temperature Stimuli-responsive polymers are used in a large variety of applications due to the controlled manner in which their physical properties can be reversibly altered. In this study, we demonstrate the thermoreversible structuring of poly-(N-isopropylacrylamide)-based polymer. By temperature-controlled atomic force microscopy, we demonstrate that polymer aggregates form on mica above the polymer lower critical solution temperature and disperse below it, and in so doing, display positional "memory" in that the nanodomains are retained in the same positions and with the same shapes during repeated cooling/heating cycles. Such positional "memory" may be useful for multiple applications in nano-microscale devices. © 2006 American Chemical Society. Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v22_n23_p9682_Pelah http://hdl.handle.net/20.500.12110/paper_07437463_v22_n23_p9682_Pelah
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Critical solution temperature
Heating cycles
Polymer aggregates
Stimuli-responsive polymers
Agglomeration
Atomic force microscopy
Functional polymers
Heating
Mica
Nanostructured materials
acrylamide derivative
aluminum silicate
mica
nanomaterial
poly(n isopropylacrylamide)
poly(N-isopropylacrylamide)
polymer
article
atomic force microscopy
chemistry
surface property
temperature
ultrastructure
Acrylamides
Aluminum Silicates
Microscopy, Atomic Force
Nanostructures
Polymers
Surface Properties
Temperature
spellingShingle Critical solution temperature
Heating cycles
Polymer aggregates
Stimuli-responsive polymers
Agglomeration
Atomic force microscopy
Functional polymers
Heating
Mica
Nanostructured materials
acrylamide derivative
aluminum silicate
mica
nanomaterial
poly(n isopropylacrylamide)
poly(N-isopropylacrylamide)
polymer
article
atomic force microscopy
chemistry
surface property
temperature
ultrastructure
Acrylamides
Aluminum Silicates
Microscopy, Atomic Force
Nanostructures
Polymers
Surface Properties
Temperature
Jares, Elizabeth Andrea
Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica
topic_facet Critical solution temperature
Heating cycles
Polymer aggregates
Stimuli-responsive polymers
Agglomeration
Atomic force microscopy
Functional polymers
Heating
Mica
Nanostructured materials
acrylamide derivative
aluminum silicate
mica
nanomaterial
poly(n isopropylacrylamide)
poly(N-isopropylacrylamide)
polymer
article
atomic force microscopy
chemistry
surface property
temperature
ultrastructure
Acrylamides
Aluminum Silicates
Microscopy, Atomic Force
Nanostructures
Polymers
Surface Properties
Temperature
description Stimuli-responsive polymers are used in a large variety of applications due to the controlled manner in which their physical properties can be reversibly altered. In this study, we demonstrate the thermoreversible structuring of poly-(N-isopropylacrylamide)-based polymer. By temperature-controlled atomic force microscopy, we demonstrate that polymer aggregates form on mica above the polymer lower critical solution temperature and disperse below it, and in so doing, display positional "memory" in that the nanodomains are retained in the same positions and with the same shapes during repeated cooling/heating cycles. Such positional "memory" may be useful for multiple applications in nano-microscale devices. © 2006 American Chemical Society.
author Jares, Elizabeth Andrea
author_facet Jares, Elizabeth Andrea
author_sort Jares, Elizabeth Andrea
title Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica
title_short Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica
title_full Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica
title_fullStr Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica
title_full_unstemmed Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica
title_sort nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica
publishDate 2006
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v22_n23_p9682_Pelah
http://hdl.handle.net/20.500.12110/paper_07437463_v22_n23_p9682_Pelah
work_keys_str_mv AT jareselizabethandrea nanoscalememoryprovidedbythermoreversiblestochasticallystructuredpolymeraggregatesonmica
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