Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica
Stimuli-responsive polymers are used in a large variety of applications due to the controlled manner in which their physical properties can be reversibly altered. In this study, we demonstrate the thermoreversible structuring of poly-(N-isopropylacrylamide)-based polymer. By temperature-controlled a...
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paper:paper_07437463_v22_n23_p9682_Pelah2023-06-08T15:44:54Z Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica Jares, Elizabeth Andrea Critical solution temperature Heating cycles Polymer aggregates Stimuli-responsive polymers Agglomeration Atomic force microscopy Functional polymers Heating Mica Nanostructured materials acrylamide derivative aluminum silicate mica nanomaterial poly(n isopropylacrylamide) poly(N-isopropylacrylamide) polymer article atomic force microscopy chemistry surface property temperature ultrastructure Acrylamides Aluminum Silicates Microscopy, Atomic Force Nanostructures Polymers Surface Properties Temperature Stimuli-responsive polymers are used in a large variety of applications due to the controlled manner in which their physical properties can be reversibly altered. In this study, we demonstrate the thermoreversible structuring of poly-(N-isopropylacrylamide)-based polymer. By temperature-controlled atomic force microscopy, we demonstrate that polymer aggregates form on mica above the polymer lower critical solution temperature and disperse below it, and in so doing, display positional "memory" in that the nanodomains are retained in the same positions and with the same shapes during repeated cooling/heating cycles. Such positional "memory" may be useful for multiple applications in nano-microscale devices. © 2006 American Chemical Society. Fil:Jares-Erijman, E.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v22_n23_p9682_Pelah http://hdl.handle.net/20.500.12110/paper_07437463_v22_n23_p9682_Pelah |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Critical solution temperature Heating cycles Polymer aggregates Stimuli-responsive polymers Agglomeration Atomic force microscopy Functional polymers Heating Mica Nanostructured materials acrylamide derivative aluminum silicate mica nanomaterial poly(n isopropylacrylamide) poly(N-isopropylacrylamide) polymer article atomic force microscopy chemistry surface property temperature ultrastructure Acrylamides Aluminum Silicates Microscopy, Atomic Force Nanostructures Polymers Surface Properties Temperature |
spellingShingle |
Critical solution temperature Heating cycles Polymer aggregates Stimuli-responsive polymers Agglomeration Atomic force microscopy Functional polymers Heating Mica Nanostructured materials acrylamide derivative aluminum silicate mica nanomaterial poly(n isopropylacrylamide) poly(N-isopropylacrylamide) polymer article atomic force microscopy chemistry surface property temperature ultrastructure Acrylamides Aluminum Silicates Microscopy, Atomic Force Nanostructures Polymers Surface Properties Temperature Jares, Elizabeth Andrea Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica |
topic_facet |
Critical solution temperature Heating cycles Polymer aggregates Stimuli-responsive polymers Agglomeration Atomic force microscopy Functional polymers Heating Mica Nanostructured materials acrylamide derivative aluminum silicate mica nanomaterial poly(n isopropylacrylamide) poly(N-isopropylacrylamide) polymer article atomic force microscopy chemistry surface property temperature ultrastructure Acrylamides Aluminum Silicates Microscopy, Atomic Force Nanostructures Polymers Surface Properties Temperature |
description |
Stimuli-responsive polymers are used in a large variety of applications due to the controlled manner in which their physical properties can be reversibly altered. In this study, we demonstrate the thermoreversible structuring of poly-(N-isopropylacrylamide)-based polymer. By temperature-controlled atomic force microscopy, we demonstrate that polymer aggregates form on mica above the polymer lower critical solution temperature and disperse below it, and in so doing, display positional "memory" in that the nanodomains are retained in the same positions and with the same shapes during repeated cooling/heating cycles. Such positional "memory" may be useful for multiple applications in nano-microscale devices. © 2006 American Chemical Society. |
author |
Jares, Elizabeth Andrea |
author_facet |
Jares, Elizabeth Andrea |
author_sort |
Jares, Elizabeth Andrea |
title |
Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica |
title_short |
Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica |
title_full |
Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica |
title_fullStr |
Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica |
title_full_unstemmed |
Nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica |
title_sort |
nanoscale memory provided by thermoreversible stochastically structured polymer aggregates on mica |
publishDate |
2006 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v22_n23_p9682_Pelah http://hdl.handle.net/20.500.12110/paper_07437463_v22_n23_p9682_Pelah |
work_keys_str_mv |
AT jareselizabethandrea nanoscalememoryprovidedbythermoreversiblestochasticallystructuredpolymeraggregatesonmica |
_version_ |
1768542892509364224 |