A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium

A flow injection hydride generation system with a metal furnace atomizer (Inconel 600® alloy) was employed for Bi and Se determination. The presented methods have linear ranges up to 200 and 500 μg L- 1 for Bi and Se, respectively, with good linearities (r2 = 0.9997 and 0.9974, respectively). The li...

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Detalles Bibliográficos
Autores principales:	Kim, Manuela Leticia, Tudino, Mabel Beatriz
Publicado:	2008
Materias:	Bi Hydride generation Metal furnace atomizer Se Absorption Atomic absorption spectrometry Atomic spectroscopy Bismuth Furnaces Metals Nonmetals Selenium Selenium compounds flow injection hydride Hydride generation atomic absorption spectrometry (HGAAS) Inconel 600 Absorption spectroscopy
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_05848547_v63_n8_p850_Klassen http://hdl.handle.net/20.500.12110/paper_05848547_v63_n8_p850_Klassen
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_05848547_v63_n8_p850_Klassen
record_format	dspace
spelling	paper:paper_05848547_v63_n8_p850_Klassen2023-06-08T15:42:46Z A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium Kim, Manuela Leticia Tudino, Mabel Beatriz Bi Hydride generation Metal furnace atomizer Se Absorption Atomic absorption spectrometry Atomic spectroscopy Bismuth Furnaces Metals Nonmetals Selenium Selenium compounds flow injection hydride Hydride generation atomic absorption spectrometry (HGAAS) Inconel 600 Absorption spectroscopy A flow injection hydride generation system with a metal furnace atomizer (Inconel 600® alloy) was employed for Bi and Se determination. The presented methods have linear ranges up to 200 and 500 μg L- 1 for Bi and Se, respectively, with good linearities (r2 = 0.9997 and 0.9974, respectively). The limits of quantification obtained according to IUPAC recommendations were 2.3 μg L- 1 for Bi and 6 μg L- 1 for Se, and the relative standard deviations (N = 6) based on Bi and Se analytical responses from real samples were 2.7% and 10%, respectively. Accuracy evaluations were based on certified materials such as SRM 361, SRM 363, and SRM 364 (steel alloys) for Bi, Mess-3 (marine sediment), SRM 397 (human hair), and Bio-Rad2 - 69042 (urine) for Se. Good agreements between the results were obtained at the 95% confidence level, according to the t-test. © 2008 Elsevier B.V. All rights reserved. Fil:Kim, M.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Tudino, M.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2008 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_05848547_v63_n8_p850_Klassen http://hdl.handle.net/20.500.12110/paper_05848547_v63_n8_p850_Klassen
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Bi Hydride generation Metal furnace atomizer Se Absorption Atomic absorption spectrometry Atomic spectroscopy Bismuth Furnaces Metals Nonmetals Selenium Selenium compounds flow injection hydride Hydride generation atomic absorption spectrometry (HGAAS) Inconel 600 Absorption spectroscopy
spellingShingle	Bi Hydride generation Metal furnace atomizer Se Absorption Atomic absorption spectrometry Atomic spectroscopy Bismuth Furnaces Metals Nonmetals Selenium Selenium compounds flow injection hydride Hydride generation atomic absorption spectrometry (HGAAS) Inconel 600 Absorption spectroscopy Kim, Manuela Leticia Tudino, Mabel Beatriz A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium
topic_facet	Bi Hydride generation Metal furnace atomizer Se Absorption Atomic absorption spectrometry Atomic spectroscopy Bismuth Furnaces Metals Nonmetals Selenium Selenium compounds flow injection hydride Hydride generation atomic absorption spectrometry (HGAAS) Inconel 600 Absorption spectroscopy
description	A flow injection hydride generation system with a metal furnace atomizer (Inconel 600® alloy) was employed for Bi and Se determination. The presented methods have linear ranges up to 200 and 500 μg L- 1 for Bi and Se, respectively, with good linearities (r2 = 0.9997 and 0.9974, respectively). The limits of quantification obtained according to IUPAC recommendations were 2.3 μg L- 1 for Bi and 6 μg L- 1 for Se, and the relative standard deviations (N = 6) based on Bi and Se analytical responses from real samples were 2.7% and 10%, respectively. Accuracy evaluations were based on certified materials such as SRM 361, SRM 363, and SRM 364 (steel alloys) for Bi, Mess-3 (marine sediment), SRM 397 (human hair), and Bio-Rad2 - 69042 (urine) for Se. Good agreements between the results were obtained at the 95% confidence level, according to the t-test. © 2008 Elsevier B.V. All rights reserved.
author	Kim, Manuela Leticia Tudino, Mabel Beatriz
author_facet	Kim, Manuela Leticia Tudino, Mabel Beatriz
author_sort	Kim, Manuela Leticia
title	A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium
title_short	A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium
title_full	A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium
title_fullStr	A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium
title_full_unstemmed	A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium
title_sort	metallic furnace atomizer in hydride generation atomic absorption spectrometry: determination of bismuth and selenium
publishDate	2008
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_05848547_v63_n8_p850_Klassen http://hdl.handle.net/20.500.12110/paper_05848547_v63_n8_p850_Klassen
work_keys_str_mv	AT kimmanuelaleticia ametallicfurnaceatomizerinhydridegenerationatomicabsorptionspectrometrydeterminationofbismuthandselenium AT tudinomabelbeatriz ametallicfurnaceatomizerinhydridegenerationatomicabsorptionspectrometrydeterminationofbismuthandselenium AT kimmanuelaleticia metallicfurnaceatomizerinhydridegenerationatomicabsorptionspectrometrydeterminationofbismuthandselenium AT tudinomabelbeatriz metallicfurnaceatomizerinhydridegenerationatomicabsorptionspectrometrydeterminationofbismuthandselenium
_version_	1768546257087758336

A metallic furnace atomizer in hydride generation atomic absorption spectrometry: Determination of bismuth and selenium

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