Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K

The static dielectric constant and density of carbon dioxide-methanol mixtures were measured at 323.15 K as a function of pressure in the range 10-18 MPa, and methanol mole fraction up to 0.16. The results, along with those obtained by other authors, allow a complete description of the dielectric an...

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Autores principales:	Goldfarb, Darío Leonardo, Fernández, Diego Pablo, Corti, Horacio Roberto
Publicado:	1999
Materias:	Carbon dioxide Density Dielectric constant Equation of state Methanol Mixture Density (specific gravity) Equations of state Permittivity Supercritical fluids Excess volume Mole fraction Phase boundary Mixtures carbon dioxide methanol chemical reaction conference paper dielectric constant mathematical analysis reaction analysis volumetry
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03783812_v158-160_n_p1011_Goldfarb http://hdl.handle.net/20.500.12110/paper_03783812_v158-160_n_p1011_Goldfarb
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_03783812_v158-160_n_p1011_Goldfarb
record_format	dspace
spelling	paper:paper_03783812_v158-160_n_p1011_Goldfarb2023-06-08T15:39:42Z Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K Goldfarb, Darío Leonardo Fernández, Diego Pablo Corti, Horacio Roberto Carbon dioxide Density Dielectric constant Equation of state Methanol Mixture Carbon dioxide Density (specific gravity) Equations of state Methanol Permittivity Supercritical fluids Excess volume Mole fraction Phase boundary Mixtures carbon dioxide methanol chemical reaction conference paper dielectric constant mathematical analysis reaction analysis volumetry The static dielectric constant and density of carbon dioxide-methanol mixtures were measured at 323.15 K as a function of pressure in the range 10-18 MPa, and methanol mole fraction up to 0.16. The results, along with those obtained by other authors, allow a complete description of the dielectric and volumetric properties of the mixture on the entire range of composition. Two empirical equations of state are presented. The first one describes the critical region, including data of the phase boundary. The second equation is valid for the entire range of composition. The excess volume is negative and its absolute value decreases as the pressure goes up. The dielectric constant increases slightly with methanol content up to mole fraction 0.2, and more steeply at higher mole fractions. © 1999 Elsevier Science B.V. All rights reserved. Fil:Goldfarb, D.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fernández, D.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Corti, H.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1999 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03783812_v158-160_n_p1011_Goldfarb http://hdl.handle.net/20.500.12110/paper_03783812_v158-160_n_p1011_Goldfarb
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Carbon dioxide Density Dielectric constant Equation of state Methanol Mixture Carbon dioxide Density (specific gravity) Equations of state Methanol Permittivity Supercritical fluids Excess volume Mole fraction Phase boundary Mixtures carbon dioxide methanol chemical reaction conference paper dielectric constant mathematical analysis reaction analysis volumetry
spellingShingle	Carbon dioxide Density Dielectric constant Equation of state Methanol Mixture Carbon dioxide Density (specific gravity) Equations of state Methanol Permittivity Supercritical fluids Excess volume Mole fraction Phase boundary Mixtures carbon dioxide methanol chemical reaction conference paper dielectric constant mathematical analysis reaction analysis volumetry Goldfarb, Darío Leonardo Fernández, Diego Pablo Corti, Horacio Roberto Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K
topic_facet	Carbon dioxide Density Dielectric constant Equation of state Methanol Mixture Carbon dioxide Density (specific gravity) Equations of state Methanol Permittivity Supercritical fluids Excess volume Mole fraction Phase boundary Mixtures carbon dioxide methanol chemical reaction conference paper dielectric constant mathematical analysis reaction analysis volumetry
description	The static dielectric constant and density of carbon dioxide-methanol mixtures were measured at 323.15 K as a function of pressure in the range 10-18 MPa, and methanol mole fraction up to 0.16. The results, along with those obtained by other authors, allow a complete description of the dielectric and volumetric properties of the mixture on the entire range of composition. Two empirical equations of state are presented. The first one describes the critical region, including data of the phase boundary. The second equation is valid for the entire range of composition. The excess volume is negative and its absolute value decreases as the pressure goes up. The dielectric constant increases slightly with methanol content up to mole fraction 0.2, and more steeply at higher mole fractions. © 1999 Elsevier Science B.V. All rights reserved.
author	Goldfarb, Darío Leonardo Fernández, Diego Pablo Corti, Horacio Roberto
author_facet	Goldfarb, Darío Leonardo Fernández, Diego Pablo Corti, Horacio Roberto
author_sort	Goldfarb, Darío Leonardo
title	Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K
title_short	Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K
title_full	Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K
title_fullStr	Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K
title_full_unstemmed	Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K
title_sort	dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 k
publishDate	1999
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03783812_v158-160_n_p1011_Goldfarb http://hdl.handle.net/20.500.12110/paper_03783812_v158-160_n_p1011_Goldfarb
work_keys_str_mv	AT goldfarbdarioleonardo dielectricandvolumetricpropertiesofsupercriticalcarbondioxide1methanol2mixturesat32315k AT fernandezdiegopablo dielectricandvolumetricpropertiesofsupercriticalcarbondioxide1methanol2mixturesat32315k AT cortihoracioroberto dielectricandvolumetricpropertiesofsupercriticalcarbondioxide1methanol2mixturesat32315k
_version_	1768546025986850816

Dielectric and volumetric properties of supercritical carbon dioxide(1) + methanol(2) mixtures at 323.15 K

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