New response in electrochemical impedance spectroscopy due to the presence of molybdenum on AB<inf>5</inf>-type alloys
During the present investigation, it was observed that the inclusion of molybdenum in LaNi<inf>3.6</inf>Co<inf>0.7</inf>Mn<inf>(0.4-x)</inf>Al<inf>0.3</inf>Mo<inf>x</inf> AB5-type alloys produced new responses in the electrochemical impedan...
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2015
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v40_n20_p6639_Diaz http://hdl.handle.net/20.500.12110/paper_03603199_v40_n20_p6639_Diaz |
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paper:paper_03603199_v40_n20_p6639_Diaz2023-06-08T15:34:42Z New response in electrochemical impedance spectroscopy due to the presence of molybdenum on AB<inf>5</inf>-type alloys Batteries Diffraction patterns Hydrogen Metal hydrides Molybdenum Alloys Charge transfer Diffraction patterns Diffusion Dynamic response Electric discharges Electrodes Hydrides Hydrogen Hydrogen storage Manganese Molybdenum Nickel metal hydride batteries Solar cells Spectroscopy Spectrum analysis X ray diffraction Anode active materials Charge transfer resistance Concentration levels Exchange current densities Hydrogen diffusion coefficients Impedance spectrum Metal hydrides Physicochemical model Electrochemical impedance spectroscopy During the present investigation, it was observed that the inclusion of molybdenum in LaNi<inf>3.6</inf>Co<inf>0.7</inf>Mn<inf>(0.4-x)</inf>Al<inf>0.3</inf>Mo<inf>x</inf> AB5-type alloys produced new responses in the electrochemical impedance spectroscopy (EIS) when they are used as an anode active material for Ni-MH batteries. The aim of this work is to study, using electrochemical impedance spectroscopy, the influence of molybdenum, on the performance of the electrode. EIS spectra were adjusted in terms of a physicochemical model of the dynamic response of the system. X ray diffraction and hydrogen diffusion coefficient calculated from discharges curves supported EIS model outcomes. The replacement of manganese by molybdenum, in a 2% w/w concentration level (AB<inf>5</inf>M1), has a positive effect for applications as energy storage material. In this sense, this alloy exhibits the lowest value of charge transfer resistance obtained from the analysis of impedance spectra. Moreover, changes in the (i<inf>0</inf>. a<inf>a</inf>) parameter, that is, the exchange current density and active area, respectively display a maximum value. The larger grade of fracture observed in AB<inf>5</inf>M1 can be due to the higher material's fragility as a consequence of molybdenum incorporation. XRD analysis on the three alloys confirms this hypothesis as shown in the paper. Copyright © 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. 2015 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v40_n20_p6639_Diaz http://hdl.handle.net/20.500.12110/paper_03603199_v40_n20_p6639_Diaz |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Batteries Diffraction patterns Hydrogen Metal hydrides Molybdenum Alloys Charge transfer Diffraction patterns Diffusion Dynamic response Electric discharges Electrodes Hydrides Hydrogen Hydrogen storage Manganese Molybdenum Nickel metal hydride batteries Solar cells Spectroscopy Spectrum analysis X ray diffraction Anode active materials Charge transfer resistance Concentration levels Exchange current densities Hydrogen diffusion coefficients Impedance spectrum Metal hydrides Physicochemical model Electrochemical impedance spectroscopy |
| spellingShingle |
Batteries Diffraction patterns Hydrogen Metal hydrides Molybdenum Alloys Charge transfer Diffraction patterns Diffusion Dynamic response Electric discharges Electrodes Hydrides Hydrogen Hydrogen storage Manganese Molybdenum Nickel metal hydride batteries Solar cells Spectroscopy Spectrum analysis X ray diffraction Anode active materials Charge transfer resistance Concentration levels Exchange current densities Hydrogen diffusion coefficients Impedance spectrum Metal hydrides Physicochemical model Electrochemical impedance spectroscopy New response in electrochemical impedance spectroscopy due to the presence of molybdenum on AB<inf>5</inf>-type alloys |
| topic_facet |
Batteries Diffraction patterns Hydrogen Metal hydrides Molybdenum Alloys Charge transfer Diffraction patterns Diffusion Dynamic response Electric discharges Electrodes Hydrides Hydrogen Hydrogen storage Manganese Molybdenum Nickel metal hydride batteries Solar cells Spectroscopy Spectrum analysis X ray diffraction Anode active materials Charge transfer resistance Concentration levels Exchange current densities Hydrogen diffusion coefficients Impedance spectrum Metal hydrides Physicochemical model Electrochemical impedance spectroscopy |
| description |
During the present investigation, it was observed that the inclusion of molybdenum in LaNi<inf>3.6</inf>Co<inf>0.7</inf>Mn<inf>(0.4-x)</inf>Al<inf>0.3</inf>Mo<inf>x</inf> AB5-type alloys produced new responses in the electrochemical impedance spectroscopy (EIS) when they are used as an anode active material for Ni-MH batteries. The aim of this work is to study, using electrochemical impedance spectroscopy, the influence of molybdenum, on the performance of the electrode. EIS spectra were adjusted in terms of a physicochemical model of the dynamic response of the system. X ray diffraction and hydrogen diffusion coefficient calculated from discharges curves supported EIS model outcomes. The replacement of manganese by molybdenum, in a 2% w/w concentration level (AB<inf>5</inf>M1), has a positive effect for applications as energy storage material. In this sense, this alloy exhibits the lowest value of charge transfer resistance obtained from the analysis of impedance spectra. Moreover, changes in the (i<inf>0</inf>. a<inf>a</inf>) parameter, that is, the exchange current density and active area, respectively display a maximum value. The larger grade of fracture observed in AB<inf>5</inf>M1 can be due to the higher material's fragility as a consequence of molybdenum incorporation. XRD analysis on the three alloys confirms this hypothesis as shown in the paper. Copyright © 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
| title |
New response in electrochemical impedance spectroscopy due to the presence of molybdenum on AB<inf>5</inf>-type alloys |
| title_short |
New response in electrochemical impedance spectroscopy due to the presence of molybdenum on AB<inf>5</inf>-type alloys |
| title_full |
New response in electrochemical impedance spectroscopy due to the presence of molybdenum on AB<inf>5</inf>-type alloys |
| title_fullStr |
New response in electrochemical impedance spectroscopy due to the presence of molybdenum on AB<inf>5</inf>-type alloys |
| title_full_unstemmed |
New response in electrochemical impedance spectroscopy due to the presence of molybdenum on AB<inf>5</inf>-type alloys |
| title_sort |
new response in electrochemical impedance spectroscopy due to the presence of molybdenum on ab<inf>5</inf>-type alloys |
| publishDate |
2015 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v40_n20_p6639_Diaz http://hdl.handle.net/20.500.12110/paper_03603199_v40_n20_p6639_Diaz |
| _version_ |
1768545557251358720 |