Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor

The kinetics of the water-gas shift reaction (WGSR) over a copper/zinc oxide/alumina catalyst have been studied. The experiments were carried out at 453-503 K and atmospheric pressure. A reactive mixture of similar composition to that employed in the industrial process was used. An integral reactor,...

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Autor principal:	Amadeo, Norma Elvira
Publicado:	1995
Materias:	Adsorption Algorithms Atmospheric pressure Carbon dioxide Carbon monoxide Catalysts Chemical reactors Computer simulation Low temperature effects Mathematical models Reaction kinetics Water Hydrogen production Industrial low-temperature converters Langmuir-Hinshelwood model Water-gas shift reaction Hydrogen
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v20_n12_p949_Amadeo http://hdl.handle.net/20.500.12110/paper_03603199_v20_n12_p949_Amadeo
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_03603199_v20_n12_p949_Amadeo
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spelling	paper:paper_03603199_v20_n12_p949_Amadeo2023-06-08T15:34:37Z Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor Amadeo, Norma Elvira Adsorption Algorithms Atmospheric pressure Carbon dioxide Carbon monoxide Catalysts Chemical reactors Computer simulation Low temperature effects Mathematical models Reaction kinetics Water Hydrogen production Industrial low-temperature converters Langmuir-Hinshelwood model Water-gas shift reaction Hydrogen The kinetics of the water-gas shift reaction (WGSR) over a copper/zinc oxide/alumina catalyst have been studied. The experiments were carried out at 453-503 K and atmospheric pressure. A reactive mixture of similar composition to that employed in the industrial process was used. An integral reactor, an integral procedure and a data treatment valid for near equilibrium conditions were employed. A number of representative models were examined. It was found that only a Langmuir-Hinshelwood model, which considers the adsorption of four species (CO, CO2, H2 and H2O) and the surface reaction as the controlling step, adequately describes the reaction behaviour at the temperature and concentration ranges investigated. Values of adsorption constants and adsorption heats for the four components involved in the WGSR are given. An algorithm for the simulation of an adiabatic fixed-bed reactor was developed with the aim of checking the kinetics expression. Both the industrial and simulated compositions agree. It is proved that the kinetic expression proposed which is in harmony with a Langmuir-Hinshelwood mechanism is useful in designing industrial low-temperature converters. © 1995. Fil:Amadeo, N.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1995 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v20_n12_p949_Amadeo http://hdl.handle.net/20.500.12110/paper_03603199_v20_n12_p949_Amadeo
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Adsorption Algorithms Atmospheric pressure Carbon dioxide Carbon monoxide Catalysts Chemical reactors Computer simulation Low temperature effects Mathematical models Reaction kinetics Water Hydrogen production Industrial low-temperature converters Langmuir-Hinshelwood model Water-gas shift reaction Hydrogen
spellingShingle	Adsorption Algorithms Atmospheric pressure Carbon dioxide Carbon monoxide Catalysts Chemical reactors Computer simulation Low temperature effects Mathematical models Reaction kinetics Water Hydrogen production Industrial low-temperature converters Langmuir-Hinshelwood model Water-gas shift reaction Hydrogen Amadeo, Norma Elvira Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor
topic_facet	Adsorption Algorithms Atmospheric pressure Carbon dioxide Carbon monoxide Catalysts Chemical reactors Computer simulation Low temperature effects Mathematical models Reaction kinetics Water Hydrogen production Industrial low-temperature converters Langmuir-Hinshelwood model Water-gas shift reaction Hydrogen
description	The kinetics of the water-gas shift reaction (WGSR) over a copper/zinc oxide/alumina catalyst have been studied. The experiments were carried out at 453-503 K and atmospheric pressure. A reactive mixture of similar composition to that employed in the industrial process was used. An integral reactor, an integral procedure and a data treatment valid for near equilibrium conditions were employed. A number of representative models were examined. It was found that only a Langmuir-Hinshelwood model, which considers the adsorption of four species (CO, CO2, H2 and H2O) and the surface reaction as the controlling step, adequately describes the reaction behaviour at the temperature and concentration ranges investigated. Values of adsorption constants and adsorption heats for the four components involved in the WGSR are given. An algorithm for the simulation of an adiabatic fixed-bed reactor was developed with the aim of checking the kinetics expression. Both the industrial and simulated compositions agree. It is proved that the kinetic expression proposed which is in harmony with a Langmuir-Hinshelwood mechanism is useful in designing industrial low-temperature converters. © 1995.
author	Amadeo, Norma Elvira
author_facet	Amadeo, Norma Elvira
author_sort	Amadeo, Norma Elvira
title	Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor
title_short	Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor
title_full	Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor
title_fullStr	Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor
title_full_unstemmed	Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor
title_sort	hydrogen production from the low-temperature water-gas shift reaction: kinetics and simulation of the industrial reactor
publishDate	1995
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03603199_v20_n12_p949_Amadeo http://hdl.handle.net/20.500.12110/paper_03603199_v20_n12_p949_Amadeo
work_keys_str_mv	AT amadeonormaelvira hydrogenproductionfromthelowtemperaturewatergasshiftreactionkineticsandsimulationoftheindustrialreactor
_version_	1768545881136562176

Hydrogen production from the low-temperature water-gas shift reaction: Kinetics and simulation of the industrial reactor

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