The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent

[Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidat...

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Detalles Bibliográficos
Autores principales:	Doctorovich, Fabio Ariel, Di Salvo, Florencia
Publicado:	2001
Materias:	Agents Amines Chemistry Chromatography Coordination reactions Iron compounds Oxidation Ruthenium compounds Benzylamine Benzylphenylmethanimine Nitrosyl Oxidation products Oxidizing agents Chemical reactions
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03404285_v26_n4-5_p505_Doctorovich http://hdl.handle.net/20.500.12110/paper_03404285_v26_n4-5_p505_Doctorovich
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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