The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent

[Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidat...

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Detalles Bibliográficos
Autores principales: Doctorovich, Fabio Ariel, Di Salvo, Florencia
Publicado: 2001
Materias:
Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03404285_v26_n4-5_p505_Doctorovich
http://hdl.handle.net/20.500.12110/paper_03404285_v26_n4-5_p505_Doctorovich
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_03404285_v26_n4-5_p505_Doctorovich
record_format dspace
spelling paper:paper_03404285_v26_n4-5_p505_Doctorovich2023-06-08T15:33:58Z The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent Doctorovich, Fabio Ariel Di Salvo, Florencia Agents Amines Chemistry Chromatography Coordination reactions Iron compounds Oxidation Ruthenium compounds Benzylamine Benzylphenylmethanimine Nitrosyl Oxidation products Oxidizing agents Chemical reactions [Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Di Salvo, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2001 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03404285_v26_n4-5_p505_Doctorovich http://hdl.handle.net/20.500.12110/paper_03404285_v26_n4-5_p505_Doctorovich
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
spellingShingle Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
Doctorovich, Fabio Ariel
Di Salvo, Florencia
The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
topic_facet Agents
Amines
Chemistry
Chromatography
Coordination reactions
Iron compounds
Oxidation
Ruthenium compounds
Benzylamine
Benzylphenylmethanimine
Nitrosyl
Oxidation products
Oxidizing agents
Chemical reactions
description [Fe(CN)5NO]2-, (1) and [Ru(bpy)2(NO)Cl]2+, (2) react with PhCH2NH2 to produce mainly N-benzylphenyl-methanimine and PhCN as oxidation products. (PhCH2)2NH, PhCH2Cl and PhCH2OH are formed as diazotization products. Products derived from the benzyl radical (such as PhMe), are also formed. Since oxidation products are generated even in the absence of oxygen, a mechanism in which the nitrosyl ligand acts as an oxidant is proposed.
author Doctorovich, Fabio Ariel
Di Salvo, Florencia
author_facet Doctorovich, Fabio Ariel
Di Salvo, Florencia
author_sort Doctorovich, Fabio Ariel
title The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_short The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_full The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_fullStr The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_full_unstemmed The reaction of [Ru(bpy)2(NO)Cl]2+ and [Fe(CN)5NO]2- with benzylamine: Coordinated nitrosyl as an oxidizing agent
title_sort reaction of [ru(bpy)2(no)cl]2+ and [fe(cn)5no]2- with benzylamine: coordinated nitrosyl as an oxidizing agent
publishDate 2001
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03404285_v26_n4-5_p505_Doctorovich
http://hdl.handle.net/20.500.12110/paper_03404285_v26_n4-5_p505_Doctorovich
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