Titania sols and gels synthesized from reverse micelles
TiO 2 nanoparticles are synthesized in water/AOT/isooctane reverse micelles by hydrolysis of titanium (IV) n-butoxide. The molar ratios of the three components defines the size of nanoparticles as determined from the uv-visible absorption onset of the disperse system. Depending on the relative conte...
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1996
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0340255X_v102_n_p51_Ginzberg http://hdl.handle.net/20.500.12110/paper_0340255X_v102_n_p51_Ginzberg |
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paper:paper_0340255X_v102_n_p51_Ginzberg2023-06-08T15:33:57Z Titania sols and gels synthesized from reverse micelles Aldabe Bilmes, Sara Alfonsina Dora Gel Nanoparticles Reverse micelles Sol-gel Titanium dioxide TiO 2 nanoparticles are synthesized in water/AOT/isooctane reverse micelles by hydrolysis of titanium (IV) n-butoxide. The molar ratios of the three components defines the size of nanoparticles as determined from the uv-visible absorption onset of the disperse system. Depending on the relative content of each component this sol undergoes a gel phase. The kinetics of sol-gel process is monitored for different Ti(BuO) 4 ./ water/AOT molar ratios, and as a function of temperature by static viscosity, and by the optical density of the system in the spectral range where light scattering is the dominant optical process. The water content of the system and the Ti(BuO) 4 /water molar ratio have great influence on the kinetics of the gelation process. An activation energy of (91 ± 9) kJmol -1 was obtained from Arrhenius plots. Fil:Bilmes, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1996 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0340255X_v102_n_p51_Ginzberg http://hdl.handle.net/20.500.12110/paper_0340255X_v102_n_p51_Ginzberg |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Gel Nanoparticles Reverse micelles Sol-gel Titanium dioxide |
spellingShingle |
Gel Nanoparticles Reverse micelles Sol-gel Titanium dioxide Aldabe Bilmes, Sara Alfonsina Dora Titania sols and gels synthesized from reverse micelles |
topic_facet |
Gel Nanoparticles Reverse micelles Sol-gel Titanium dioxide |
description |
TiO 2 nanoparticles are synthesized in water/AOT/isooctane reverse micelles by hydrolysis of titanium (IV) n-butoxide. The molar ratios of the three components defines the size of nanoparticles as determined from the uv-visible absorption onset of the disperse system. Depending on the relative content of each component this sol undergoes a gel phase. The kinetics of sol-gel process is monitored for different Ti(BuO) 4 ./ water/AOT molar ratios, and as a function of temperature by static viscosity, and by the optical density of the system in the spectral range where light scattering is the dominant optical process. The water content of the system and the Ti(BuO) 4 /water molar ratio have great influence on the kinetics of the gelation process. An activation energy of (91 ± 9) kJmol -1 was obtained from Arrhenius plots. |
author |
Aldabe Bilmes, Sara Alfonsina Dora |
author_facet |
Aldabe Bilmes, Sara Alfonsina Dora |
author_sort |
Aldabe Bilmes, Sara Alfonsina Dora |
title |
Titania sols and gels synthesized from reverse micelles |
title_short |
Titania sols and gels synthesized from reverse micelles |
title_full |
Titania sols and gels synthesized from reverse micelles |
title_fullStr |
Titania sols and gels synthesized from reverse micelles |
title_full_unstemmed |
Titania sols and gels synthesized from reverse micelles |
title_sort |
titania sols and gels synthesized from reverse micelles |
publishDate |
1996 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0340255X_v102_n_p51_Ginzberg http://hdl.handle.net/20.500.12110/paper_0340255X_v102_n_p51_Ginzberg |
work_keys_str_mv |
AT aldabebilmessaraalfonsinadora titaniasolsandgelssynthesizedfromreversemicelles |
_version_ |
1768543036732604416 |