Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)

Three novel zinc(II) oxydiacetate (oda) compounds [{Zn(oda)·0.3H2O}n] 1, [Zn(oda)(bipy)(H2O)]·2.5H2O 2 (bipy = 2,2′-bipyridine) and [Zn(oda)(phen)(H2O)]·1.5H2O 3 (phen = 1,10-phenanthroline) have been synthesized and their structures determined by single-crystal X-ray diffraction methods. Compound 1...

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Autores principales: Baggio, Ricardo F., Perec, Mireille
Publicado: 1996
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009246_v_n13_p2747_Baggio
http://hdl.handle.net/20.500.12110/paper_03009246_v_n13_p2747_Baggio
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paper:paper_03009246_v_n13_p2747_Baggio2023-06-08T15:27:35Z Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline) Baggio, Ricardo F. Perec, Mireille Three novel zinc(II) oxydiacetate (oda) compounds [{Zn(oda)·0.3H2O}n] 1, [Zn(oda)(bipy)(H2O)]·2.5H2O 2 (bipy = 2,2′-bipyridine) and [Zn(oda)(phen)(H2O)]·1.5H2O 3 (phen = 1,10-phenanthroline) have been synthesized and their structures determined by single-crystal X-ray diffraction methods. Compound 1 consists of polymeric sheets formed by ZnO5 units bridged by carboxylate groups in anti-syn conformation along the z axis; 2 and 3 are mononuclear with the zinc atoms in distorted octahedral ZnN2O4 co-ordination geometries. Thermal decomposition of the compounds under an oxygen atmosphere affords ZnO at ca. 500°C. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1996 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009246_v_n13_p2747_Baggio http://hdl.handle.net/20.500.12110/paper_03009246_v_n13_p2747_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Three novel zinc(II) oxydiacetate (oda) compounds [{Zn(oda)·0.3H2O}n] 1, [Zn(oda)(bipy)(H2O)]·2.5H2O 2 (bipy = 2,2′-bipyridine) and [Zn(oda)(phen)(H2O)]·1.5H2O 3 (phen = 1,10-phenanthroline) have been synthesized and their structures determined by single-crystal X-ray diffraction methods. Compound 1 consists of polymeric sheets formed by ZnO5 units bridged by carboxylate groups in anti-syn conformation along the z axis; 2 and 3 are mononuclear with the zinc atoms in distorted octahedral ZnN2O4 co-ordination geometries. Thermal decomposition of the compounds under an oxygen atmosphere affords ZnO at ca. 500°C.
author Baggio, Ricardo F.
Perec, Mireille
spellingShingle Baggio, Ricardo F.
Perec, Mireille
Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
author_facet Baggio, Ricardo F.
Perec, Mireille
author_sort Baggio, Ricardo F.
title Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_short Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_full Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_fullStr Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_full_unstemmed Synthesis and characterization of zinc(II) oxydiacetate (oda) complexes. Crystal structures of [{Zn(oda)·0.3H2O}n], [Zn(oda)(bipy)(H2O)]·2.5H2O and [Zn(oda)(phen)(H2O)]·1.5H2O (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
title_sort synthesis and characterization of zinc(ii) oxydiacetate (oda) complexes. crystal structures of [{zn(oda)·0.3h2o}n], [zn(oda)(bipy)(h2o)]·2.5h2o and [zn(oda)(phen)(h2o)]·1.5h2o (bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline)
publishDate 1996
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009246_v_n13_p2747_Baggio
http://hdl.handle.net/20.500.12110/paper_03009246_v_n13_p2747_Baggio
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AT perecmireille synthesisandcharacterizationofzinciioxydiacetateodacomplexescrystalstructuresofznoda03h2onznodabipyh2o25h2oandznodaphenh2o15h2obipy22bipyridinephen110phenanthroline
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