Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes

[MmFe(CN)5L·xH2O] (M = Mn, Fe, Co, Ni, Cu; L = pyridine or pyrazine derivative) have been synthesized, and their UV-vis and IR spectral characteristics are reported. Thermolysis of the solids leads to water release, ligand release and/or decomposition, redox interaction between Fe3+ (or Cu2+) with C...

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Autor principal: Sileo, Elsa Ester
Publicado: 1987
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v6_n9_p1757_Sileo
http://hdl.handle.net/20.500.12110/paper_02775387_v6_n9_p1757_Sileo
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_02775387_v6_n9_p1757_Sileo
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spelling paper:paper_02775387_v6_n9_p1757_Sileo2023-06-08T15:26:06Z Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes Sileo, Elsa Ester [MmFe(CN)5L·xH2O] (M = Mn, Fe, Co, Ni, Cu; L = pyridine or pyrazine derivative) have been synthesized, and their UV-vis and IR spectral characteristics are reported. Thermolysis of the solids leads to water release, ligand release and/or decomposition, redox interaction between Fe3+ (or Cu2+) with CN- or L, and redox interaction between M2+ (or Cu+) and CN-, yielding elemental metal and metal carbides. © 1987. Fil:Sileo, E.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1987 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v6_n9_p1757_Sileo http://hdl.handle.net/20.500.12110/paper_02775387_v6_n9_p1757_Sileo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description [MmFe(CN)5L·xH2O] (M = Mn, Fe, Co, Ni, Cu; L = pyridine or pyrazine derivative) have been synthesized, and their UV-vis and IR spectral characteristics are reported. Thermolysis of the solids leads to water release, ligand release and/or decomposition, redox interaction between Fe3+ (or Cu2+) with CN- or L, and redox interaction between M2+ (or Cu+) and CN-, yielding elemental metal and metal carbides. © 1987.
author Sileo, Elsa Ester
spellingShingle Sileo, Elsa Ester
Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes
author_facet Sileo, Elsa Ester
author_sort Sileo, Elsa Ester
title Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes
title_short Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes
title_full Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes
title_fullStr Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes
title_full_unstemmed Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes
title_sort synthesis and thermal behaviour of a series of pentacyanoligandferrate(ii) complexes
publishDate 1987
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v6_n9_p1757_Sileo
http://hdl.handle.net/20.500.12110/paper_02775387_v6_n9_p1757_Sileo
work_keys_str_mv AT sileoelsaester synthesisandthermalbehaviourofaseriesofpentacyanoligandferrateiicomplexes
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