Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)

Studies of the reaction of lithium morpholide with N,N-dibutylformamide and 1-formyl-piperidine, respectively, indicate that in the complex equilibria resulting from these compounds the mixed diamino lithium alkoxides derived from morpholine and the corresponding amide (N,N-dibutylformamide or 1-for...

Descripción completa

Detalles Bibliográficos
Autor principal: Schulz, Hernán Gustavo
Publicado: 1998
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v17_n2_p146_Nudelman
http://hdl.handle.net/20.500.12110/paper_02767333_v17_n2_p146_Nudelman
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_02767333_v17_n2_p146_Nudelman
record_format dspace
spelling paper:paper_02767333_v17_n2_p146_Nudelman2023-06-08T15:25:54Z Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H) Schulz, Hernán Gustavo Studies of the reaction of lithium morpholide with N,N-dibutylformamide and 1-formyl-piperidine, respectively, indicate that in the complex equilibria resulting from these compounds the mixed diamino lithium alkoxides derived from morpholine and the corresponding amide (N,N-dibutylformamide or 1-formylpiperidine) are formed first. These intermediates then collapse to the lithium morpholide carbamoyl anion which reacts with morpholine to finally give the lithium dimorpholinemethoxide, which was detected by 13C NMR as well as independently synthesized. Fil:Schulz, H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1998 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v17_n2_p146_Nudelman http://hdl.handle.net/20.500.12110/paper_02767333_v17_n2_p146_Nudelman
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Studies of the reaction of lithium morpholide with N,N-dibutylformamide and 1-formyl-piperidine, respectively, indicate that in the complex equilibria resulting from these compounds the mixed diamino lithium alkoxides derived from morpholine and the corresponding amide (N,N-dibutylformamide or 1-formylpiperidine) are formed first. These intermediates then collapse to the lithium morpholide carbamoyl anion which reacts with morpholine to finally give the lithium dimorpholinemethoxide, which was detected by 13C NMR as well as independently synthesized.
author Schulz, Hernán Gustavo
spellingShingle Schulz, Hernán Gustavo
Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
author_facet Schulz, Hernán Gustavo
author_sort Schulz, Hernán Gustavo
title Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_short Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_full Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_fullStr Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_full_unstemmed Further insights into the chemistry of acyllithium compounds R2NC(O)Li: Characterization of an amide (R2NLi) adduct (R2NCHNR2(OLi)) to a formamide (R2NC(O)H)
title_sort further insights into the chemistry of acyllithium compounds r2nc(o)li: characterization of an amide (r2nli) adduct (r2nchnr2(oli)) to a formamide (r2nc(o)h)
publishDate 1998
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v17_n2_p146_Nudelman
http://hdl.handle.net/20.500.12110/paper_02767333_v17_n2_p146_Nudelman
work_keys_str_mv AT schulzhernangustavo furtherinsightsintothechemistryofacyllithiumcompoundsr2ncolicharacterizationofanamider2nliadductr2nchnr2olitoaformamider2ncoh
_version_ 1768545049990135808

Ejemplares similares