Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system

Samples of cured medium cis polybutadiene compound, formulated with sulphur and accelerator and vulcanized at 433 K, were prepared at different cure times in order to obtain different network structures. Uniaxial stress strain tests were performed at room temperature and analyzed in the frame of the...

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Detalles Bibliográficos
Autores principales:	Marzocca, Angel José, Goyanes, Silvia Nair
Publicado:	2010
Materias:	Polybutadiene rubber Swelling Toluene Vulcanization
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02556952_v30_n1_p67_Marzocca http://hdl.handle.net/20.500.12110/paper_02556952_v30_n1_p67_Marzocca
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_02556952_v30_n1_p67_Marzocca
record_format	dspace
spelling	paper:paper_02556952_v30_n1_p67_Marzocca2023-06-08T15:22:03Z Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system Marzocca, Angel José Goyanes, Silvia Nair Polybutadiene rubber Swelling Toluene Vulcanization Samples of cured medium cis polybutadiene compound, formulated with sulphur and accelerator and vulcanized at 433 K, were prepared at different cure times in order to obtain different network structures. Uniaxial stress strain tests were performed at room temperature and analyzed in the frame of the tube model and the molecular weight between crosslinks was obtained. Swelling tests in toluene at room temperature were made in the same samples and the volume fraction of rubber was calculated in each case. By means of the Flory-Rehner relationship and using the molecular weight between crosslinks, the Flory's parameter χ was estimated for the polybutadiene/toluene system. © 2010 Universidad Simón Bolívar (Venezuela). Fil:Marzocca, A.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Goyanes, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2010 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02556952_v30_n1_p67_Marzocca http://hdl.handle.net/20.500.12110/paper_02556952_v30_n1_p67_Marzocca
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Polybutadiene rubber Swelling Toluene Vulcanization
spellingShingle	Polybutadiene rubber Swelling Toluene Vulcanization Marzocca, Angel José Goyanes, Silvia Nair Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system
topic_facet	Polybutadiene rubber Swelling Toluene Vulcanization
description	Samples of cured medium cis polybutadiene compound, formulated with sulphur and accelerator and vulcanized at 433 K, were prepared at different cure times in order to obtain different network structures. Uniaxial stress strain tests were performed at room temperature and analyzed in the frame of the tube model and the molecular weight between crosslinks was obtained. Swelling tests in toluene at room temperature were made in the same samples and the volume fraction of rubber was calculated in each case. By means of the Flory-Rehner relationship and using the molecular weight between crosslinks, the Flory's parameter χ was estimated for the polybutadiene/toluene system. © 2010 Universidad Simón Bolívar (Venezuela).
author	Marzocca, Angel José Goyanes, Silvia Nair
author_facet	Marzocca, Angel José Goyanes, Silvia Nair
author_sort	Marzocca, Angel José
title	Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system
title_short	Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system
title_full	Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system
title_fullStr	Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system
title_full_unstemmed	Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system
title_sort	influence of the reticulation structure on the coefficiency of flory interaction in polybutadiene/toluene system
publishDate	2010
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02556952_v30_n1_p67_Marzocca http://hdl.handle.net/20.500.12110/paper_02556952_v30_n1_p67_Marzocca
work_keys_str_mv	AT marzoccaangeljose influenceofthereticulationstructureonthecoefficiencyoffloryinteractioninpolybutadienetoluenesystem AT goyanessilvianair influenceofthereticulationstructureonthecoefficiencyoffloryinteractioninpolybutadienetoluenesystem
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Influence of the reticulation structure on the coefficiency of Flory interaction in polybutadiene/toluene system

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