N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds

The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinate...

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Detalles Bibliográficos
Autores principales:	Suarez, Sebastian, Doctorovich, Fabio Ariel
Publicado:	2011
Materias:	Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v67_n10_po417_Suarez http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_01082701_v67_n10_po417_Suarez
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spelling	paper:paper_01082701_v67_n10_po417_Suarez2023-06-08T15:10:43Z N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds Suarez, Sebastian Doctorovich, Fabio Ariel Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography. Fil:Suarez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2011 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v67_n10_po417_Suarez http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions
spellingShingle	Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions Suarez, Sebastian Doctorovich, Fabio Ariel N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
topic_facet	Asymmetric unit Carborane anions Carborane cages Counterions Pyridinium salts Title compounds Positive ions Negative ions
description	The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography.
author	Suarez, Sebastian Doctorovich, Fabio Ariel
author_facet	Suarez, Sebastian Doctorovich, Fabio Ariel
author_sort	Suarez, Sebastian
title	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_short	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_full	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_fullStr	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_full_unstemmed	N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
title_sort	n-butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
publishDate	2011
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v67_n10_po417_Suarez http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez
work_keys_str_mv	AT suarezsebastian nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds AT doctorovichfabioariel nbutylpyridiniumundecachlorocarbadodecaborateandcomparisonwithsimilarcompounds
_version_	1768545873627709440

N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds

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