A new polymeric phase of zinc(II) oxydiacetate

A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presen...

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Detalles Bibliográficos
Autor principal: Perec, Mireille
Publicado: 2003
Materias:
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v59_n1_pm30_Baggio
http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio
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id paper:paper_01082701_v59_n1_pm30_Baggio
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spelling paper:paper_01082701_v59_n1_pm30_Baggio2023-06-08T15:10:40Z A new polymeric phase of zinc(II) oxydiacetate Perec, Mireille Carboxylic acids Crystal structure Crystallography Hydrogen bonds Molecular structure Polymers Zinc compounds Polymeric phases Organometallics Catena A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presents a chain-like structure, generated by ZnO6 cores which are bridged by carboxylate groups in an anti-anti conformation along the unique crystallographic b axis. The chains are held together through hydrogen-bonding interactions with the three water molecules. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2003 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v59_n1_pm30_Baggio http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Carboxylic acids
Crystal structure
Crystallography
Hydrogen bonds
Molecular structure
Polymers
Zinc compounds
Polymeric phases
Organometallics
Catena
spellingShingle Carboxylic acids
Crystal structure
Crystallography
Hydrogen bonds
Molecular structure
Polymers
Zinc compounds
Polymeric phases
Organometallics
Catena
Perec, Mireille
A new polymeric phase of zinc(II) oxydiacetate
topic_facet Carboxylic acids
Crystal structure
Crystallography
Hydrogen bonds
Molecular structure
Polymers
Zinc compounds
Polymeric phases
Organometallics
Catena
description A new polymeric phase of zinc(II) oxydiacetate, catena-poly[[[diaquazinc(II)]-μ-oxydiacetato] hydrate], {[Zn(C4H4-O5)(H2O)2] ·H2O}n, isomorphous with the Co homologue [Hatfield, Helms, Rohrs, Singh, Wasson & Weller (1987). Proc. Indian Acad. Sci. Chem. Sci. 98, 23-31], is reported. It presents a chain-like structure, generated by ZnO6 cores which are bridged by carboxylate groups in an anti-anti conformation along the unique crystallographic b axis. The chains are held together through hydrogen-bonding interactions with the three water molecules.
author Perec, Mireille
author_facet Perec, Mireille
author_sort Perec, Mireille
title A new polymeric phase of zinc(II) oxydiacetate
title_short A new polymeric phase of zinc(II) oxydiacetate
title_full A new polymeric phase of zinc(II) oxydiacetate
title_fullStr A new polymeric phase of zinc(II) oxydiacetate
title_full_unstemmed A new polymeric phase of zinc(II) oxydiacetate
title_sort new polymeric phase of zinc(ii) oxydiacetate
publishDate 2003
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v59_n1_pm30_Baggio
http://hdl.handle.net/20.500.12110/paper_01082701_v59_n1_pm30_Baggio
work_keys_str_mv AT perecmireille anewpolymericphaseofzinciioxydiacetate
AT perecmireille newpolymericphaseofzinciioxydiacetate
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