Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate

The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all t...

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Autores principales: Perec, Mireille, Baggio, Ricardo F.
Publicado: 1999
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v55_n6_p858_Perec
http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_01082701_v55_n6_p858_Perec
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spelling paper:paper_01082701_v55_n6_p858_Perec2023-06-08T15:10:39Z Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate Perec, Mireille Baggio, Ricardo F. The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1999 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v55_n6_p858_Perec http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The crystal structure of the title complex, [Ni(C3H4N2)6](C4H 4O5)·C2H5OH, is a tightly woven three-dimensional network composed of [Ni(Him)6]2+ cations (Him is imidazole) interlinked by the oxydiacetate anion through six different N-H⋯O bonds, in which all the N-H imidazole groups, as well as all the carboxylate O atoms, take part. This structure is the first to show an [Ni(Him)6]2+ group which does not display any crystallographic symmetry. © 1999 International Union of Crystallography.
author Perec, Mireille
Baggio, Ricardo F.
spellingShingle Perec, Mireille
Baggio, Ricardo F.
Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
author_facet Perec, Mireille
Baggio, Ricardo F.
author_sort Perec, Mireille
title Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_short Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_full Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_fullStr Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_full_unstemmed Hexakis(imidazole-N3)nickel(II) oxydiacetate ethanol solvate
title_sort hexakis(imidazole-n3)nickel(ii) oxydiacetate ethanol solvate
publishDate 1999
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v55_n6_p858_Perec
http://hdl.handle.net/20.500.12110/paper_01082701_v55_n6_p858_Perec
work_keys_str_mv AT perecmireille hexakisimidazolen3nickeliioxydiacetateethanolsolvate
AT baggioricardof hexakisimidazolen3nickeliioxydiacetateethanolsolvate
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