Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update

The thermodynamics of dissolution of non-reactive gases in water under ambient conditions is of importance for the description of the properties of small hydrophobic solutes, and they are also of interest for environmental assessments. The review published in 1977 by Wilhelm, Battino and Wilcock (Ch...

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Autor principal: Fernandez Prini, Roberto
Publicado: 2008
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00959782_v37_n10_p1379_Alvarez
http://hdl.handle.net/20.500.12110/paper_00959782_v37_n10_p1379_Alvarez
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spelling paper:paper_00959782_v37_n10_p1379_Alvarez2023-06-08T15:09:44Z Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update Fernandez Prini, Roberto Ambient temperatures Aqueous solutions Gaseous solutes Gibbs energy and enthalpy of dissolution The thermodynamics of dissolution of non-reactive gases in water under ambient conditions is of importance for the description of the properties of small hydrophobic solutes, and they are also of interest for environmental assessments. The review published in 1977 by Wilhelm, Battino and Wilcock (Chem. Rev. 77:219-262, 1977) constitutes a milestone in this field. However, a number of new data have been published since then, including both solubility and calorimetric determinations. We have analyzed the new data for 27 binary systems reported in the literature at the time of writing this article. Whenever solubility and calorimetric data both exist they have been fitted together. There are, however, systems for which only one type of new thermodynamic information is available; these systems were also analyzed using procedures that are described in this work. © 2008 Springer Science+Business Media, LLC. Fil:Fernández Prini, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2008 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00959782_v37_n10_p1379_Alvarez http://hdl.handle.net/20.500.12110/paper_00959782_v37_n10_p1379_Alvarez
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Ambient temperatures
Aqueous solutions
Gaseous solutes
Gibbs energy and enthalpy of dissolution
spellingShingle Ambient temperatures
Aqueous solutions
Gaseous solutes
Gibbs energy and enthalpy of dissolution
Fernandez Prini, Roberto
Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update
topic_facet Ambient temperatures
Aqueous solutions
Gaseous solutes
Gibbs energy and enthalpy of dissolution
description The thermodynamics of dissolution of non-reactive gases in water under ambient conditions is of importance for the description of the properties of small hydrophobic solutes, and they are also of interest for environmental assessments. The review published in 1977 by Wilhelm, Battino and Wilcock (Chem. Rev. 77:219-262, 1977) constitutes a milestone in this field. However, a number of new data have been published since then, including both solubility and calorimetric determinations. We have analyzed the new data for 27 binary systems reported in the literature at the time of writing this article. Whenever solubility and calorimetric data both exist they have been fitted together. There are, however, systems for which only one type of new thermodynamic information is available; these systems were also analyzed using procedures that are described in this work. © 2008 Springer Science+Business Media, LLC.
author Fernandez Prini, Roberto
author_facet Fernandez Prini, Roberto
author_sort Fernandez Prini, Roberto
title Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update
title_short Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update
title_full Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update
title_fullStr Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update
title_full_unstemmed Thermodynamics of non-reactive gases dissolved in water at ambient temperature (T≤333 K): An update
title_sort thermodynamics of non-reactive gases dissolved in water at ambient temperature (t≤333 k): an update
publishDate 2008
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00959782_v37_n10_p1379_Alvarez
http://hdl.handle.net/20.500.12110/paper_00959782_v37_n10_p1379_Alvarez
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