Study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness
Polycrystalline titanium thin films have been widely employed as interlayer between the substrate and different coatings in order to improve adhesion strength, corrosion resistance and wear performance, as well as to promote the growth of crystalline phases of the coating. The thickness of the Ti la...
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2015
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00406090_v593_n_p110_Fazio http://hdl.handle.net/20.500.12110/paper_00406090_v593_n_p110_Fazio |
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paper:paper_00406090_v593_n_p110_Fazio2023-06-08T15:04:37Z Study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness Fazio, Mariana Andrea Kleiman, Ariel Javier Franco Arias, Lina Maria Marquez, Adriana B. Face centered cubic titanium phase Films Thin films Titanium Vacuum arc discharge Coatings Corrosion resistance Crystal structure Film growth Films Hardening Monocrystalline silicon Silicon wafers Titanium Vacuum applications Vacuum technology Wear resistance Critical thickness Crystalline phasis Deposition process Face-centered cubic Polycrystalline titanium Preferred orientations Titanium thin films Vacuum arc discharges Thin films Polycrystalline titanium thin films have been widely employed as interlayer between the substrate and different coatings in order to improve adhesion strength, corrosion resistance and wear performance, as well as to promote the growth of crystalline phases of the coating. The thickness of the Ti layer can be relevant on the behavior of the coatings, however very few studies have been carried out. In this work, the crystal structure of polycrystalline titanium films deposited with a vacuum arc discharge on monocrystalline silicon wafers (100) was studied and a dependence on the film thickness was found. The presence of the fcc phase of titanium was observed for the thinnest films with a critical thickness estimated in 300 nm, a much larger value than those reported for other deposition processes. For larger thicknesses, the films grew as α-titanium with a preferred orientation in the [100] direction. The obtained results agreed with a growth model based on the matching between the film and the substrate lattice. The characteristics of the films deposited in two steps, which had not been previously investigated, reinforced the suggested model. © 2015 Elsevier B.V. Fil:Fazio, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Kleiman, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Franco Arias, L.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Márquez, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2015 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00406090_v593_n_p110_Fazio http://hdl.handle.net/20.500.12110/paper_00406090_v593_n_p110_Fazio |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Face centered cubic titanium phase Films Thin films Titanium Vacuum arc discharge Coatings Corrosion resistance Crystal structure Film growth Films Hardening Monocrystalline silicon Silicon wafers Titanium Vacuum applications Vacuum technology Wear resistance Critical thickness Crystalline phasis Deposition process Face-centered cubic Polycrystalline titanium Preferred orientations Titanium thin films Vacuum arc discharges Thin films |
| spellingShingle |
Face centered cubic titanium phase Films Thin films Titanium Vacuum arc discharge Coatings Corrosion resistance Crystal structure Film growth Films Hardening Monocrystalline silicon Silicon wafers Titanium Vacuum applications Vacuum technology Wear resistance Critical thickness Crystalline phasis Deposition process Face-centered cubic Polycrystalline titanium Preferred orientations Titanium thin films Vacuum arc discharges Thin films Fazio, Mariana Andrea Kleiman, Ariel Javier Franco Arias, Lina Maria Marquez, Adriana B. Study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness |
| topic_facet |
Face centered cubic titanium phase Films Thin films Titanium Vacuum arc discharge Coatings Corrosion resistance Crystal structure Film growth Films Hardening Monocrystalline silicon Silicon wafers Titanium Vacuum applications Vacuum technology Wear resistance Critical thickness Crystalline phasis Deposition process Face-centered cubic Polycrystalline titanium Preferred orientations Titanium thin films Vacuum arc discharges Thin films |
| description |
Polycrystalline titanium thin films have been widely employed as interlayer between the substrate and different coatings in order to improve adhesion strength, corrosion resistance and wear performance, as well as to promote the growth of crystalline phases of the coating. The thickness of the Ti layer can be relevant on the behavior of the coatings, however very few studies have been carried out. In this work, the crystal structure of polycrystalline titanium films deposited with a vacuum arc discharge on monocrystalline silicon wafers (100) was studied and a dependence on the film thickness was found. The presence of the fcc phase of titanium was observed for the thinnest films with a critical thickness estimated in 300 nm, a much larger value than those reported for other deposition processes. For larger thicknesses, the films grew as α-titanium with a preferred orientation in the [100] direction. The obtained results agreed with a growth model based on the matching between the film and the substrate lattice. The characteristics of the films deposited in two steps, which had not been previously investigated, reinforced the suggested model. © 2015 Elsevier B.V. |
| author |
Fazio, Mariana Andrea Kleiman, Ariel Javier Franco Arias, Lina Maria Marquez, Adriana B. |
| author_facet |
Fazio, Mariana Andrea Kleiman, Ariel Javier Franco Arias, Lina Maria Marquez, Adriana B. |
| author_sort |
Fazio, Mariana Andrea |
| title |
Study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness |
| title_short |
Study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness |
| title_full |
Study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness |
| title_fullStr |
Study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness |
| title_full_unstemmed |
Study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness |
| title_sort |
study of the structure of titanium thin films deposited with a vacuum arc as a function of the thickness |
| publishDate |
2015 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00406090_v593_n_p110_Fazio http://hdl.handle.net/20.500.12110/paper_00406090_v593_n_p110_Fazio |
| work_keys_str_mv |
AT faziomarianaandrea studyofthestructureoftitaniumthinfilmsdepositedwithavacuumarcasafunctionofthethickness AT kleimanarieljavier studyofthestructureoftitaniumthinfilmsdepositedwithavacuumarcasafunctionofthethickness AT francoariaslinamaria studyofthestructureoftitaniumthinfilmsdepositedwithavacuumarcasafunctionofthethickness AT marquezadrianab studyofthestructureoftitaniumthinfilmsdepositedwithavacuumarcasafunctionofthethickness |
| _version_ |
1768546012320759808 |