The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines

Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce...

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Publicado:	1999
Materias:	Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v40_n25_p4635_Doctorovich http://hdl.handle.net/20.500.12110/paper_00404039_v40_n25_p4635_Doctorovich
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00404039_v40_n25_p4635_Doctorovich
record_format	dspace
spelling	paper:paper_00404039_v40_n25_p4635_Doctorovich2023-06-08T15:04:25Z The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce dibenzylamine and piperidine, respectively. 1999 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v40_n25_p4635_Doctorovich http://hdl.handle.net/20.500.12110/paper_00404039_v40_n25_p4635_Doctorovich
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis
spellingShingle	Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines
topic_facet	Amine Complex Diazotization Iron Nitroprusside Pentacyanonitrosylferrate aliphatic compound amine benzylamine butylamine coordination compound diazonium compound dibenzylamine dibutylamine iron derivative metal pentacyanonitrosylferrate(ii) piperidine putrescine unclassified drug article chemical reaction reaction analysis synthesis
description	Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce dibenzylamine and piperidine, respectively.
title	The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines
title_short	The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines
title_full	The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines
title_fullStr	The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines
title_full_unstemmed	The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines
title_sort	reaction of pentacyanonitrosylferrate(ii) with primary amines as a source of stabilized aliphatic diazonium ions: a new route to secondary amines
publishDate	1999
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v40_n25_p4635_Doctorovich http://hdl.handle.net/20.500.12110/paper_00404039_v40_n25_p4635_Doctorovich
_version_	1768544813076971520

The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: A new route to secondary amines

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