Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane

A synthetic approach to 12(13→18)-abeo-pregnanes by base catalyzed rearrangement of a 12,18-cyclopregnane-11,20-dione is described. The latter steroid was prepared by means of a hypoiodite type reaction.

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Detalles Bibliográficos
Autores principales:	Ferrara, Andrés, Burton, Gerardo
Publicado:	1996
Materias:	pregnane derivative article drug synthesis reaction analysis
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v37_n7_p929_Ferrara http://hdl.handle.net/20.500.12110/paper_00404039_v37_n7_p929_Ferrara
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00404039_v37_n7_p929_Ferrara
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spelling	paper:paper_00404039_v37_n7_p929_Ferrara2025-07-30T17:44:57Z Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane Ferrara, Andrés Burton, Gerardo pregnane derivative article drug synthesis reaction analysis A synthetic approach to 12(13→18)-abeo-pregnanes by base catalyzed rearrangement of a 12,18-cyclopregnane-11,20-dione is described. The latter steroid was prepared by means of a hypoiodite type reaction. Fil:Ferrara, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Burton, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1996 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v37_n7_p929_Ferrara http://hdl.handle.net/20.500.12110/paper_00404039_v37_n7_p929_Ferrara
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	pregnane derivative article drug synthesis reaction analysis
spellingShingle	pregnane derivative article drug synthesis reaction analysis Ferrara, Andrés Burton, Gerardo Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
topic_facet	pregnane derivative article drug synthesis reaction analysis
description	A synthetic approach to 12(13→18)-abeo-pregnanes by base catalyzed rearrangement of a 12,18-cyclopregnane-11,20-dione is described. The latter steroid was prepared by means of a hypoiodite type reaction.
author	Ferrara, Andrés Burton, Gerardo
author_facet	Ferrara, Andrés Burton, Gerardo
author_sort	Ferrara, Andrés
title	Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_short	Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_full	Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_fullStr	Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_full_unstemmed	Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane
title_sort	ring expansion of fused cyclopropylketones. synthesis of a 12(13→18)-abeo-pregnane
publishDate	1996
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v37_n7_p929_Ferrara http://hdl.handle.net/20.500.12110/paper_00404039_v37_n7_p929_Ferrara
work_keys_str_mv	AT ferraraandres ringexpansionoffusedcyclopropylketonessynthesisofa121318abeopregnane AT burtongerardo ringexpansionoffusedcyclopropylketonessynthesisofa121318abeopregnane
_version_	1840326326044590080

Ring expansion of fused cyclopropylketones. Synthesis of a 12(13→18)-abeo-pregnane

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