Unusual dealkylations and rearrangements in aromatic nucleophilic substitution

The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and...

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Autor principal: Socolovsky, Susana Emilia
Publicado: 1980
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v21_n35_p3331_Nudelman
http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00404039_v21_n35_p3331_Nudelman
record_format dspace
spelling paper:paper_00404039_v21_n35_p3331_Nudelman2025-07-30T17:44:53Z Unusual dealkylations and rearrangements in aromatic nucleophilic substitution Socolovsky, Susana Emilia The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine. A carbanionic mechanism is proposed. © 1980. Fil:Socolovsky, S.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1980 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v21_n35_p3331_Nudelman http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine. A carbanionic mechanism is proposed. © 1980.
author Socolovsky, Susana Emilia
spellingShingle Socolovsky, Susana Emilia
Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
author_facet Socolovsky, Susana Emilia
author_sort Socolovsky, Susana Emilia
title Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_short Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_full Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_fullStr Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_full_unstemmed Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
title_sort unusual dealkylations and rearrangements in aromatic nucleophilic substitution
publishDate 1980
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v21_n35_p3331_Nudelman
http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman
work_keys_str_mv AT socolovskysusanaemilia unusualdealkylationsandrearrangementsinaromaticnucleophilicsubstitution
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