Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+

The reaction of [Ru(bpy)2(NO)Cl]2+ with 2,2,2-trifluoroethylamine produced [Ru(bpy)2(NO)Cl]+ by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed res...

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Detalles Bibliográficos
Autores principales: Di Salvo, Florencia, Crespo, Alejandro, Estrin, Dario Ariel, Doctorovich, Fabio Ariel
Publicado: 2002
Materias:
2,2,2-trifluoroethylamine
Complex
Density functional theory
Electron transfer
n-butylamine
Nitrosyl
Ruthenium
2,2,2 trifluoroethylamine
butylamine
ethylamine
ruthenium complex
unclassified drug
article
calculation
chemical reaction
complex formation
electron transport
molecular stability
priority journal
reaction analysis
solvation
theory
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v58_n21_p4237_DiSalvo
http://hdl.handle.net/20.500.12110/paper_00404020_v58_n21_p4237_DiSalvo
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:The reaction of [Ru(bpy)2(NO)Cl]2+ with 2,2,2-trifluoroethylamine produced [Ru(bpy)2(NO)Cl]+ by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed results suggest that stabilization of the trifluoroethyldiazonium ion by complexation is much larger than the one corresponding to the butyl ion, in agreement with the fact that no rearrangement products derived from CF3CH2+ were observed. © 2002 Elsevier Science Ltd. All rights reserved.

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