Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+

The reaction of [Ru(bpy)2(NO)Cl]2+ with 2,2,2-trifluoroethylamine produced [Ru(bpy)2(NO)Cl]+ by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed res...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Di Salvo, Florencia, Crespo, Alejandro, Estrin, Dario Ariel, Doctorovich, Fabio Ariel
Publicado:	2002
Materias:	2,2,2-trifluoroethylamine Complex Density functional theory Electron transfer n-butylamine Nitrosyl Ruthenium 2,2,2 trifluoroethylamine butylamine ethylamine ruthenium complex unclassified drug article calculation chemical reaction complex formation electron transport molecular stability priority journal reaction analysis solvation theory
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v58_n21_p4237_DiSalvo http://hdl.handle.net/20.500.12110/paper_00404020_v58_n21_p4237_DiSalvo
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00404020_v58_n21_p4237_DiSalvo
record_format	dspace
spelling	paper:paper_00404020_v58_n21_p4237_DiSalvo2023-06-08T15:04:15Z Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+ Di Salvo, Florencia Crespo, Alejandro Estrin, Dario Ariel Doctorovich, Fabio Ariel 2,2,2-trifluoroethylamine Complex Density functional theory Electron transfer n-butylamine Nitrosyl Ruthenium 2,2,2 trifluoroethylamine butylamine ethylamine ruthenium complex unclassified drug article calculation chemical reaction complex formation electron transport molecular stability priority journal reaction analysis solvation theory The reaction of [Ru(bpy)2(NO)Cl]2+ with 2,2,2-trifluoroethylamine produced [Ru(bpy)2(NO)Cl]+ by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed results suggest that stabilization of the trifluoroethyldiazonium ion by complexation is much larger than the one corresponding to the butyl ion, in agreement with the fact that no rearrangement products derived from CF3CH2+ were observed. © 2002 Elsevier Science Ltd. All rights reserved. Fil:Di Salvo, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Crespo, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Estrin, D.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2002 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v58_n21_p4237_DiSalvo http://hdl.handle.net/20.500.12110/paper_00404020_v58_n21_p4237_DiSalvo
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	2,2,2-trifluoroethylamine Complex Density functional theory Electron transfer n-butylamine Nitrosyl Ruthenium 2,2,2 trifluoroethylamine butylamine ethylamine ruthenium complex unclassified drug article calculation chemical reaction complex formation electron transport molecular stability priority journal reaction analysis solvation theory
spellingShingle	2,2,2-trifluoroethylamine Complex Density functional theory Electron transfer n-butylamine Nitrosyl Ruthenium 2,2,2 trifluoroethylamine butylamine ethylamine ruthenium complex unclassified drug article calculation chemical reaction complex formation electron transport molecular stability priority journal reaction analysis solvation theory Di Salvo, Florencia Crespo, Alejandro Estrin, Dario Ariel Doctorovich, Fabio Ariel Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+
topic_facet	2,2,2-trifluoroethylamine Complex Density functional theory Electron transfer n-butylamine Nitrosyl Ruthenium 2,2,2 trifluoroethylamine butylamine ethylamine ruthenium complex unclassified drug article calculation chemical reaction complex formation electron transport molecular stability priority journal reaction analysis solvation theory
description	The reaction of [Ru(bpy)2(NO)Cl]2+ with 2,2,2-trifluoroethylamine produced [Ru(bpy)2(NO)Cl]+ by electron transfer and a number of organic compounds formed via nucleophilic substitution of the intermediate 2,2,2-trifluoroethyldiazonium ion (free or coordinated). Density functional theory computed results suggest that stabilization of the trifluoroethyldiazonium ion by complexation is much larger than the one corresponding to the butyl ion, in agreement with the fact that no rearrangement products derived from CF3CH2+ were observed. © 2002 Elsevier Science Ltd. All rights reserved.
author	Di Salvo, Florencia Crespo, Alejandro Estrin, Dario Ariel Doctorovich, Fabio Ariel
author_facet	Di Salvo, Florencia Crespo, Alejandro Estrin, Dario Ariel Doctorovich, Fabio Ariel
author_sort	Di Salvo, Florencia
title	Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+
title_short	Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+
title_full	Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+
title_fullStr	Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+
title_full_unstemmed	Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+
title_sort	reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [ru(bpy)2(no)cl]2+
publishDate	2002
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v58_n21_p4237_DiSalvo http://hdl.handle.net/20.500.12110/paper_00404020_v58_n21_p4237_DiSalvo
work_keys_str_mv	AT disalvoflorencia reactionpathwaysof222trifluoroethylamineandnbutylaminewithrubpy2nocl2 AT crespoalejandro reactionpathwaysof222trifluoroethylamineandnbutylaminewithrubpy2nocl2 AT estrindarioariel reactionpathwaysof222trifluoroethylamineandnbutylaminewithrubpy2nocl2 AT doctorovichfabioariel reactionpathwaysof222trifluoroethylamineandnbutylaminewithrubpy2nocl2
_version_	1768543362268266496

Reaction pathways of 2,2,2-trifluoroethylamine and n-butylamine with [Ru(bpy)2(NO)Cl]2+

Ejemplares similares