A facile synthesis of 4-(3β -methoxy-5α -androstan-17β -yl)- 3-pyrrolin-2-one
The title compound was prepared in 4 steps from 3β-methoxy-21- hydroxy-5α-pregnan-20-one (1). The required intermediate (4) was obtained using lithium enolate derived from t-butyl acetate. Interesting enough, p-tosyl chloride in pyridine quantitatively converted compound 1 into the a-chloro ketone d...
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| Autores principales: | Revelli, Gustavo Ariel, Gros, Eduardo Gervasio |
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| Publicado: |
1993
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| Materias: | |
| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00397911_v23_n8_p1111_Revelli http://hdl.handle.net/20.500.12110/paper_00397911_v23_n8_p1111_Revelli |
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