New C-secosteroids from the gorgonian Tripalea clavaria

Seven new C-secosteroids were isolated from the gorgonian Tripalea clavaria collected from the South Atlantic. These compounds have a Δ5, 9,11-secosteroid nucleus together with a 22S hydroxyl group. The absolute configuration of the 22-hydroxyl group was determined with the help of COSY spectra of t...

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Autores principales: Rodríguez Brasco, María Florencia, Palermo, Jorge Alejandro
Publicado: 2007
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v72_n14_p908_RodriguezBrasco
http://hdl.handle.net/20.500.12110/paper_0039128X_v72_n14_p908_RodriguezBrasco
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spelling paper:paper_0039128X_v72_n14_p908_RodriguezBrasco2023-06-08T15:03:18Z New C-secosteroids from the gorgonian Tripalea clavaria Rodríguez Brasco, María Florencia Palermo, Jorge Alejandro Gorgonian Marine sterols Secosteroids Tripalea clavaria 3beta acetoxy 11,21,22 trihydroxy 9,11 secocholest 5 en 9 one 3beta acetoxy 11,22 dihydroxy 9,11 secocholest 5 en 9 one 3beta acetoxy 11,22 dihydroxy 9,11 secoergost 5,24(28) dien 9 one 3beta,11 dihydroxy 9,11 seco 24 norcholest 5 en 9 one 3beta,11,21,22 tetrahydroxy 9,11 secocholest 5 en 9 one 3beta,11,22 trihydroxy 9,11 secocholest 5 en 9 one 3beta,11,22 trihydroxy 9,11 secocholest 5,24 dien 9 one secosteroid unclassified drug antibiotic sensitivity antimicrobial activity article carbon nuclear magnetic resonance coelenterate drug isolation drug structure nonhuman proton nuclear magnetic resonance Staphylococcus aureus Tripalea clavaria Animals Anthozoa Anti-Bacterial Agents Antibiotics, Antifungal Bacillus subtilis Botrytis Candida albicans Escherichia coli Magnetic Resonance Spectroscopy Molecular Structure Secosteroids Staphylococcus aureus Gorgonia Tripalea clavaria Seven new C-secosteroids were isolated from the gorgonian Tripalea clavaria collected from the South Atlantic. These compounds have a Δ5, 9,11-secosteroid nucleus together with a 22S hydroxyl group. The absolute configuration of the 22-hydroxyl group was determined with the help of COSY spectra of the Mosher esters of the compounds. © 2007 Elsevier Inc. All rights reserved. Fil:Rodríguez Brasco, M.F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Palermo, J.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2007 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v72_n14_p908_RodriguezBrasco http://hdl.handle.net/20.500.12110/paper_0039128X_v72_n14_p908_RodriguezBrasco
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Gorgonian
Marine sterols
Secosteroids
Tripalea clavaria
3beta acetoxy 11,21,22 trihydroxy 9,11 secocholest 5 en 9 one
3beta acetoxy 11,22 dihydroxy 9,11 secocholest 5 en 9 one
3beta acetoxy 11,22 dihydroxy 9,11 secoergost 5,24(28) dien 9 one
3beta,11 dihydroxy 9,11 seco 24 norcholest 5 en 9 one
3beta,11,21,22 tetrahydroxy 9,11 secocholest 5 en 9 one
3beta,11,22 trihydroxy 9,11 secocholest 5 en 9 one
3beta,11,22 trihydroxy 9,11 secocholest 5,24 dien 9 one
secosteroid
unclassified drug
antibiotic sensitivity
antimicrobial activity
article
carbon nuclear magnetic resonance
coelenterate
drug isolation
drug structure
nonhuman
proton nuclear magnetic resonance
Staphylococcus aureus
Tripalea clavaria
Animals
Anthozoa
Anti-Bacterial Agents
Antibiotics, Antifungal
Bacillus subtilis
Botrytis
Candida albicans
Escherichia coli
Magnetic Resonance Spectroscopy
Molecular Structure
Secosteroids
Staphylococcus aureus
Gorgonia
Tripalea clavaria
spellingShingle Gorgonian
Marine sterols
Secosteroids
Tripalea clavaria
3beta acetoxy 11,21,22 trihydroxy 9,11 secocholest 5 en 9 one
3beta acetoxy 11,22 dihydroxy 9,11 secocholest 5 en 9 one
3beta acetoxy 11,22 dihydroxy 9,11 secoergost 5,24(28) dien 9 one
3beta,11 dihydroxy 9,11 seco 24 norcholest 5 en 9 one
3beta,11,21,22 tetrahydroxy 9,11 secocholest 5 en 9 one
3beta,11,22 trihydroxy 9,11 secocholest 5 en 9 one
3beta,11,22 trihydroxy 9,11 secocholest 5,24 dien 9 one
secosteroid
unclassified drug
antibiotic sensitivity
antimicrobial activity
article
carbon nuclear magnetic resonance
coelenterate
drug isolation
drug structure
nonhuman
proton nuclear magnetic resonance
Staphylococcus aureus
Tripalea clavaria
Animals
Anthozoa
Anti-Bacterial Agents
Antibiotics, Antifungal
Bacillus subtilis
Botrytis
Candida albicans
Escherichia coli
Magnetic Resonance Spectroscopy
Molecular Structure
Secosteroids
Staphylococcus aureus
Gorgonia
Tripalea clavaria
Rodríguez Brasco, María Florencia
Palermo, Jorge Alejandro
New C-secosteroids from the gorgonian Tripalea clavaria
topic_facet Gorgonian
Marine sterols
Secosteroids
Tripalea clavaria
3beta acetoxy 11,21,22 trihydroxy 9,11 secocholest 5 en 9 one
3beta acetoxy 11,22 dihydroxy 9,11 secocholest 5 en 9 one
3beta acetoxy 11,22 dihydroxy 9,11 secoergost 5,24(28) dien 9 one
3beta,11 dihydroxy 9,11 seco 24 norcholest 5 en 9 one
3beta,11,21,22 tetrahydroxy 9,11 secocholest 5 en 9 one
3beta,11,22 trihydroxy 9,11 secocholest 5 en 9 one
3beta,11,22 trihydroxy 9,11 secocholest 5,24 dien 9 one
secosteroid
unclassified drug
antibiotic sensitivity
antimicrobial activity
article
carbon nuclear magnetic resonance
coelenterate
drug isolation
drug structure
nonhuman
proton nuclear magnetic resonance
Staphylococcus aureus
Tripalea clavaria
Animals
Anthozoa
Anti-Bacterial Agents
Antibiotics, Antifungal
Bacillus subtilis
Botrytis
Candida albicans
Escherichia coli
Magnetic Resonance Spectroscopy
Molecular Structure
Secosteroids
Staphylococcus aureus
Gorgonia
Tripalea clavaria
description Seven new C-secosteroids were isolated from the gorgonian Tripalea clavaria collected from the South Atlantic. These compounds have a Δ5, 9,11-secosteroid nucleus together with a 22S hydroxyl group. The absolute configuration of the 22-hydroxyl group was determined with the help of COSY spectra of the Mosher esters of the compounds. © 2007 Elsevier Inc. All rights reserved.
author Rodríguez Brasco, María Florencia
Palermo, Jorge Alejandro
author_facet Rodríguez Brasco, María Florencia
Palermo, Jorge Alejandro
author_sort Rodríguez Brasco, María Florencia
title New C-secosteroids from the gorgonian Tripalea clavaria
title_short New C-secosteroids from the gorgonian Tripalea clavaria
title_full New C-secosteroids from the gorgonian Tripalea clavaria
title_fullStr New C-secosteroids from the gorgonian Tripalea clavaria
title_full_unstemmed New C-secosteroids from the gorgonian Tripalea clavaria
title_sort new c-secosteroids from the gorgonian tripalea clavaria
publishDate 2007
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v72_n14_p908_RodriguezBrasco
http://hdl.handle.net/20.500.12110/paper_0039128X_v72_n14_p908_RodriguezBrasco
work_keys_str_mv AT rodriguezbrascomariaflorencia newcsecosteroidsfromthegorgoniantripaleaclavaria
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