Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material

Several acrylic copolymers containing, at random, sequences of poly(ethyl acrylate) and poly(N-(2-hydroxyethyl)acrylamide) were obtained from ethyl acrylate as the only monomer starting material in a chain polymerization process, catalyzed by Candida antarctica lipase B. In the presence of ethanolam...

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Autores principales:	Rustoy, Eduardo Miguel, Erra Balsells, Rosa, Baldessari, Alicia
Publicado:	2007
Materias:	Chain polymerization Ethyl acrylate Lipase-catalyzed Catalysis Fourier transform infrared spectroscopy Living polymerization Monomers Nuclear magnetic resonance spectroscopy Synthesis (chemical) Acrylic copolymers Copolymers catalyst copolymer monomer polyacrylamide polyacrylate polymerization synthesis
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00323861_v48_n6_p1517_Rustoy http://hdl.handle.net/20.500.12110/paper_00323861_v48_n6_p1517_Rustoy
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00323861_v48_n6_p1517_Rustoy
record_format	dspace
spelling	paper:paper_00323861_v48_n6_p1517_Rustoy2023-06-08T15:00:12Z Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material Rustoy, Eduardo Miguel Erra Balsells, Rosa Baldessari, Alicia Chain polymerization Ethyl acrylate Lipase-catalyzed Catalysis Fourier transform infrared spectroscopy Living polymerization Monomers Nuclear magnetic resonance spectroscopy Synthesis (chemical) Acrylic copolymers Chain polymerization Ethyl acrylate Lipase-catalyzed Copolymers catalyst copolymer monomer polyacrylamide polyacrylate polymerization synthesis Several acrylic copolymers containing, at random, sequences of poly(ethyl acrylate) and poly(N-(2-hydroxyethyl)acrylamide) were obtained from ethyl acrylate as the only monomer starting material in a chain polymerization process, catalyzed by Candida antarctica lipase B. In the presence of ethanolamine, the enzyme not only catalyzes the chain polymerization of ethyl acrylate but also aminolysis the pendant ester groups. The products, characterized by FTIR, 1H and 13C NMR and UV-MALDI-TOF-MS, show low molecular weight and high monodispersity. The activity showed by C. antarctica lipase B in the polymerization reaction is a new example of enzyme promiscuity. © 2007 Elsevier Ltd. All rights reserved. Fil:Rustoy, E.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Baldessari, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2007 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00323861_v48_n6_p1517_Rustoy http://hdl.handle.net/20.500.12110/paper_00323861_v48_n6_p1517_Rustoy
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Chain polymerization Ethyl acrylate Lipase-catalyzed Catalysis Fourier transform infrared spectroscopy Living polymerization Monomers Nuclear magnetic resonance spectroscopy Synthesis (chemical) Acrylic copolymers Chain polymerization Ethyl acrylate Lipase-catalyzed Copolymers catalyst copolymer monomer polyacrylamide polyacrylate polymerization synthesis
spellingShingle	Chain polymerization Ethyl acrylate Lipase-catalyzed Catalysis Fourier transform infrared spectroscopy Living polymerization Monomers Nuclear magnetic resonance spectroscopy Synthesis (chemical) Acrylic copolymers Chain polymerization Ethyl acrylate Lipase-catalyzed Copolymers catalyst copolymer monomer polyacrylamide polyacrylate polymerization synthesis Rustoy, Eduardo Miguel Erra Balsells, Rosa Baldessari, Alicia Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material
topic_facet	Chain polymerization Ethyl acrylate Lipase-catalyzed Catalysis Fourier transform infrared spectroscopy Living polymerization Monomers Nuclear magnetic resonance spectroscopy Synthesis (chemical) Acrylic copolymers Chain polymerization Ethyl acrylate Lipase-catalyzed Copolymers catalyst copolymer monomer polyacrylamide polyacrylate polymerization synthesis
description	Several acrylic copolymers containing, at random, sequences of poly(ethyl acrylate) and poly(N-(2-hydroxyethyl)acrylamide) were obtained from ethyl acrylate as the only monomer starting material in a chain polymerization process, catalyzed by Candida antarctica lipase B. In the presence of ethanolamine, the enzyme not only catalyzes the chain polymerization of ethyl acrylate but also aminolysis the pendant ester groups. The products, characterized by FTIR, 1H and 13C NMR and UV-MALDI-TOF-MS, show low molecular weight and high monodispersity. The activity showed by C. antarctica lipase B in the polymerization reaction is a new example of enzyme promiscuity. © 2007 Elsevier Ltd. All rights reserved.
author	Rustoy, Eduardo Miguel Erra Balsells, Rosa Baldessari, Alicia
author_facet	Rustoy, Eduardo Miguel Erra Balsells, Rosa Baldessari, Alicia
author_sort	Rustoy, Eduardo Miguel
title	Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material
title_short	Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material
title_full	Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material
title_fullStr	Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material
title_full_unstemmed	Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material
title_sort	lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material
publishDate	2007
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00323861_v48_n6_p1517_Rustoy http://hdl.handle.net/20.500.12110/paper_00323861_v48_n6_p1517_Rustoy
work_keys_str_mv	AT rustoyeduardomiguel lipasecatalyzedsynthesisandcharacterizationofcopolymersfromethylacrylateastheonlymonomerstartingmaterial AT errabalsellsrosa lipasecatalyzedsynthesisandcharacterizationofcopolymersfromethylacrylateastheonlymonomerstartingmaterial AT baldessarialicia lipasecatalyzedsynthesisandcharacterizationofcopolymersfromethylacrylateastheonlymonomerstartingmaterial
_version_	1768543458044149760

Lipase-catalyzed synthesis and characterization of copolymers from ethyl acrylate as the only monomer starting material

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