Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol

Feeding experiments with [24-14C] 24-methylenecholesterol and mixtures of this sterol and [7-3H] 24-methylenecholesterol were performed to study the biosynthesis of withanolides in the plant Acnistus breviflorus. The results indicate that the side chain of the sterol precursor should be broken betwe...

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Autores principales: Monteagudo, Edith Sandra, Burton, Gerardo, Gros, Eduardo Gervasio
Publicado: 1994
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v35_n4_p927_Monteagudo
http://hdl.handle.net/20.500.12110/paper_00319422_v35_n4_p927_Monteagudo
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spelling paper:paper_00319422_v35_n4_p927_Monteagudo2023-06-08T14:59:30Z Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol Monteagudo, Edith Sandra Burton, Gerardo Gros, Eduardo Gervasio 24-methylenecholesterol Acnistus breviflorus biosynthesis. jaborosalactone A jaborosalactone D Solanaceae withaferin A withanolides Feeding experiments with [24-14C] 24-methylenecholesterol and mixtures of this sterol and [7-3H] 24-methylenecholesterol were performed to study the biosynthesis of withanolides in the plant Acnistus breviflorus. The results indicate that the side chain of the sterol precursor should be broken between C-24 and C-25 to give an intermediate which follows the biogenetic pathway into withaferin A, jaborosalactone A and jaborosalactone D. © 1994. Fil:Monteagudo, E.S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Burton, G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1994 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v35_n4_p927_Monteagudo http://hdl.handle.net/20.500.12110/paper_00319422_v35_n4_p927_Monteagudo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic 24-methylenecholesterol
Acnistus breviflorus
biosynthesis.
jaborosalactone A
jaborosalactone D
Solanaceae
withaferin A
withanolides
spellingShingle 24-methylenecholesterol
Acnistus breviflorus
biosynthesis.
jaborosalactone A
jaborosalactone D
Solanaceae
withaferin A
withanolides
Monteagudo, Edith Sandra
Burton, Gerardo
Gros, Eduardo Gervasio
Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
topic_facet 24-methylenecholesterol
Acnistus breviflorus
biosynthesis.
jaborosalactone A
jaborosalactone D
Solanaceae
withaferin A
withanolides
description Feeding experiments with [24-14C] 24-methylenecholesterol and mixtures of this sterol and [7-3H] 24-methylenecholesterol were performed to study the biosynthesis of withanolides in the plant Acnistus breviflorus. The results indicate that the side chain of the sterol precursor should be broken between C-24 and C-25 to give an intermediate which follows the biogenetic pathway into withaferin A, jaborosalactone A and jaborosalactone D. © 1994.
author Monteagudo, Edith Sandra
Burton, Gerardo
Gros, Eduardo Gervasio
author_facet Monteagudo, Edith Sandra
Burton, Gerardo
Gros, Eduardo Gervasio
author_sort Monteagudo, Edith Sandra
title Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_short Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_full Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_fullStr Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_full_unstemmed Biosynthesis of withanolides in Acnistus breviflorus. Incorporation of labelled 24-methylenecholesterol
title_sort biosynthesis of withanolides in acnistus breviflorus. incorporation of labelled 24-methylenecholesterol
publishDate 1994
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v35_n4_p927_Monteagudo
http://hdl.handle.net/20.500.12110/paper_00319422_v35_n4_p927_Monteagudo
work_keys_str_mv AT monteagudoedithsandra biosynthesisofwithanolidesinacnistusbreviflorusincorporationoflabelled24methylenecholesterol
AT burtongerardo biosynthesisofwithanolidesinacnistusbreviflorusincorporationoflabelled24methylenecholesterol
AT groseduardogervasio biosynthesisofwithanolidesinacnistusbreviflorusincorporationoflabelled24methylenecholesterol
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