Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]

THE usual reaction product of the treatment of the acylated nitriles of aldonic acids with ammonia are the aldose diacetamides1. A variation of this reaction was found when Hockett and Chandler2, by treating hexa-acetyl-D-α-glucoheptonic acid nitrile with ammonia, obtained N-acetyl-D-glucofuranosyla...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Deulofeu, Venancio, Deferrari, Jorge O.
Publicado: 1951
Materias:
glucose
article
GLUCOSE
Glucose
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00280836_v167_n4236_p42_Deulofeu
http://hdl.handle.net/20.500.12110/paper_00280836_v167_n4236_p42_Deulofeu
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00280836_v167_n4236_p42_Deulofeu
record_format dspace
spelling paper:paper_00280836_v167_n4236_p42_Deulofeu2023-06-08T14:54:39Z Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19] Deulofeu, Venancio Deferrari, Jorge O. glucose article GLUCOSE Glucose THE usual reaction product of the treatment of the acylated nitriles of aldonic acids with ammonia are the aldose diacetamides1. A variation of this reaction was found when Hockett and Chandler2, by treating hexa-acetyl-D-α-glucoheptonic acid nitrile with ammonia, obtained N-acetyl-D-glucofuranosylamine. The same product resulted from the action of ammonia on penta-acetyl-aldehydo-D-glucose. Later, Niemann and Hays3 prepared N-acetyl-D-glucofuranosylamine by the action of methanolic ammonia on penta-acetyl-D-β-glucose, a reaction that produced the transformation of the original pyranose ring of the acetylated glucose into a furanose structure. © 1951 Nature Publishing Group. Fil:Deulofeu, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1951 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00280836_v167_n4236_p42_Deulofeu http://hdl.handle.net/20.500.12110/paper_00280836_v167_n4236_p42_Deulofeu
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic glucose
article
GLUCOSE
Glucose
spellingShingle glucose
article
GLUCOSE
Glucose
Deulofeu, Venancio
Deferrari, Jorge O.
Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
topic_facet glucose
article
GLUCOSE
Glucose
description THE usual reaction product of the treatment of the acylated nitriles of aldonic acids with ammonia are the aldose diacetamides1. A variation of this reaction was found when Hockett and Chandler2, by treating hexa-acetyl-D-α-glucoheptonic acid nitrile with ammonia, obtained N-acetyl-D-glucofuranosylamine. The same product resulted from the action of ammonia on penta-acetyl-aldehydo-D-glucose. Later, Niemann and Hays3 prepared N-acetyl-D-glucofuranosylamine by the action of methanolic ammonia on penta-acetyl-D-β-glucose, a reaction that produced the transformation of the original pyranose ring of the acetylated glucose into a furanose structure. © 1951 Nature Publishing Group.
author Deulofeu, Venancio
Deferrari, Jorge O.
author_facet Deulofeu, Venancio
Deferrari, Jorge O.
author_sort Deulofeu, Venancio
title Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_short Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_full Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_fullStr Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_full_unstemmed Preparation of D-glucose dibenzamide from pentabenzoyl-D-α-glucose [19]
title_sort preparation of d-glucose dibenzamide from pentabenzoyl-d-α-glucose [19]
publishDate 1951
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00280836_v167_n4236_p42_Deulofeu
http://hdl.handle.net/20.500.12110/paper_00280836_v167_n4236_p42_Deulofeu
work_keys_str_mv AT deulofeuvenancio preparationofdglucosedibenzamidefrompentabenzoyldaglucose19
AT deferrarijorgeo preparationofdglucosedibenzamidefrompentabenzoyldaglucose19
_version_ 1768545273159614464

Ejemplares similares