On the pressure dependence of the effective ionic charge of cesium halides
The importance of temperature effects in the use of the second Szigeti relation to calculate the volume dependence of the effective ionic charge of cesium halide crystals is studied. The effect obtained is larger than the one for alkali halide crystals of the NaCl structure. Positive values of (∂ ln...
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1980
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223697_v41_n8_p863_Batana http://hdl.handle.net/20.500.12110/paper_00223697_v41_n8_p863_Batana |
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paper:paper_00223697_v41_n8_p863_Batana2023-06-08T14:50:15Z On the pressure dependence of the effective ionic charge of cesium halides Batana, Alicia CESIUM COMPOUNDS The importance of temperature effects in the use of the second Szigeti relation to calculate the volume dependence of the effective ionic charge of cesium halide crystals is studied. The effect obtained is larger than the one for alkali halide crystals of the NaCl structure. Positive values of (∂ ln s/∂ In v) are obtained using low temperature experimental data with the Grüineisen parameter γt(T → 0K) calculated using the generalized first Szigeti relation. Values of γt are also obtained with a rigid ion model and they differ little from the previous ones. © 1980. Fil:Batana, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1980 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223697_v41_n8_p863_Batana http://hdl.handle.net/20.500.12110/paper_00223697_v41_n8_p863_Batana |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
CESIUM COMPOUNDS |
spellingShingle |
CESIUM COMPOUNDS Batana, Alicia On the pressure dependence of the effective ionic charge of cesium halides |
topic_facet |
CESIUM COMPOUNDS |
description |
The importance of temperature effects in the use of the second Szigeti relation to calculate the volume dependence of the effective ionic charge of cesium halide crystals is studied. The effect obtained is larger than the one for alkali halide crystals of the NaCl structure. Positive values of (∂ ln s/∂ In v) are obtained using low temperature experimental data with the Grüineisen parameter γt(T → 0K) calculated using the generalized first Szigeti relation. Values of γt are also obtained with a rigid ion model and they differ little from the previous ones. © 1980. |
author |
Batana, Alicia |
author_facet |
Batana, Alicia |
author_sort |
Batana, Alicia |
title |
On the pressure dependence of the effective ionic charge of cesium halides |
title_short |
On the pressure dependence of the effective ionic charge of cesium halides |
title_full |
On the pressure dependence of the effective ionic charge of cesium halides |
title_fullStr |
On the pressure dependence of the effective ionic charge of cesium halides |
title_full_unstemmed |
On the pressure dependence of the effective ionic charge of cesium halides |
title_sort |
on the pressure dependence of the effective ionic charge of cesium halides |
publishDate |
1980 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223697_v41_n8_p863_Batana http://hdl.handle.net/20.500.12110/paper_00223697_v41_n8_p863_Batana |
work_keys_str_mv |
AT batanaalicia onthepressuredependenceoftheeffectiveionicchargeofcesiumhalides |
_version_ |
1768542632713125888 |