ortho Effects on Nucleophilic Aromatic Substitution. The Reactions of 6-R-2-Nitrochlorobenzenes with Piperidine in Benzene
The rate constants and thermodynamic parameters for the reaction of nine 6-R-2-nitrochlorobenzenes with piperidine in benzene have been determined. The reactions follow the Hammett relationship log (kR/kH) = σρ if the "bulky" substituents, bromine and methyl, are excluded. An approximate v...
Guardado en:
| Publicado: |
1965
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v30_n10_p3365_Sbarbati http://hdl.handle.net/20.500.12110/paper_00223263_v30_n10_p3365_Sbarbati |
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