The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation

1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar t...

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Detalles Bibliográficos
Autores principales: Deulofeu, Venancio, Deferrari, Jorge O.
Publicado: 1952
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v17_n8_p1087_Deulofeu
http://hdl.handle.net/20.500.12110/paper_00223263_v17_n8_p1087_Deulofeu
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00223263_v17_n8_p1087_Deulofeu
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spelling paper:paper_00223263_v17_n8_p1087_Deulofeu2023-06-08T14:49:20Z The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation Deulofeu, Venancio Deferrari, Jorge O. 1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar to that obtained from the epimer, hexaacetyl-d-gluco-d-gulo-heptonic nitrile. 3. A discussion is given of the mechanism of the reaction. © 1952, American Chemical Society. All rights reserved. Fil:Deulofeu, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1952 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v17_n8_p1087_Deulofeu http://hdl.handle.net/20.500.12110/paper_00223263_v17_n8_p1087_Deulofeu
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description 1. By the action of methanolic ammonia on the α- and β-isomers of pentabenzoyl-d-glucose, d-glucose dibenzamide is obtained in almost the same yield. 2. When hexaacetyl-d-gluco-d-ido-heptonic nitrile is treated with methanolic ammonia, N-acetyl-d-glucofuranosylamine is produced, in a yield similar to that obtained from the epimer, hexaacetyl-d-gluco-d-gulo-heptonic nitrile. 3. A discussion is given of the mechanism of the reaction. © 1952, American Chemical Society. All rights reserved.
author Deulofeu, Venancio
Deferrari, Jorge O.
spellingShingle Deulofeu, Venancio
Deferrari, Jorge O.
The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
author_facet Deulofeu, Venancio
Deferrari, Jorge O.
author_sort Deulofeu, Venancio
title The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
title_short The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
title_full The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
title_fullStr The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
title_full_unstemmed The reaction of ammonia with some acetylated and benzoylated monosaccharides. I. d-glucose derivatives and an interpretation
title_sort reaction of ammonia with some acetylated and benzoylated monosaccharides. i. d-glucose derivatives and an interpretation
publishDate 1952
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00223263_v17_n8_p1087_Deulofeu
http://hdl.handle.net/20.500.12110/paper_00223263_v17_n8_p1087_Deulofeu
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AT deferrarijorgeo thereactionofammoniawithsomeacetylatedandbenzoylatedmonosaccharidesidglucosederivativesandaninterpretation
AT deulofeuvenancio reactionofammoniawithsomeacetylatedandbenzoylatedmonosaccharidesidglucosederivativesandaninterpretation
AT deferrarijorgeo reactionofammoniawithsomeacetylatedandbenzoylatedmonosaccharidesidglucosederivativesandaninterpretation
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