Solvation dynamics following electron photodetachment from l- in aqueous clusters

New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the micr...

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Detalles Bibliográficos
Autores principales: Elola, María Dolores, Laria, Daniel Hector
Publicado: 2002
Materias:
Algorithms
Chemical relaxation
Diffusion
Electronic properties
Ground state
Mathematical models
Molecular structure
Photochemical reactions
Quantum theory
Solutions
Diffuse density profile
Electron photodetachment
Electronic excitation
Equilibrium solvation structures
Solvation dynamics
Surface states
Molecular dynamics
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v117_n5_p2238_Elola
http://hdl.handle.net/20.500.12110/paper_00219606_v117_n5_p2238_Elola
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00219606_v117_n5_p2238_Elola
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spelling paper:paper_00219606_v117_n5_p2238_Elola2023-06-08T14:44:05Z Solvation dynamics following electron photodetachment from l- in aqueous clusters Elola, María Dolores Laria, Daniel Hector Algorithms Chemical relaxation Diffusion Electronic properties Ground state Mathematical models Molecular structure Photochemical reactions Quantum theory Solutions Diffuse density profile Electron photodetachment Electronic excitation Equilibrium solvation structures Solvation dynamics Surface states Molecular dynamics New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the microscopic mechanisms that drive the reaction. These fluctuations, in turn, determine the characteristics of the electron localization and the subsequent detachment following photoexcitation of the probe. Fil:Elola, M.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Laria, D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2002 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v117_n5_p2238_Elola http://hdl.handle.net/20.500.12110/paper_00219606_v117_n5_p2238_Elola
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Algorithms
Chemical relaxation
Diffusion
Electronic properties
Ground state
Mathematical models
Molecular structure
Photochemical reactions
Quantum theory
Solutions
Diffuse density profile
Electron photodetachment
Electronic excitation
Equilibrium solvation structures
Solvation dynamics
Surface states
Molecular dynamics
spellingShingle Algorithms
Chemical relaxation
Diffusion
Electronic properties
Ground state
Mathematical models
Molecular structure
Photochemical reactions
Quantum theory
Solutions
Diffuse density profile
Electron photodetachment
Electronic excitation
Equilibrium solvation structures
Solvation dynamics
Surface states
Molecular dynamics
Elola, María Dolores
Laria, Daniel Hector
Solvation dynamics following electron photodetachment from l- in aqueous clusters
topic_facet Algorithms
Chemical relaxation
Diffusion
Electronic properties
Ground state
Mathematical models
Molecular structure
Photochemical reactions
Quantum theory
Solutions
Diffuse density profile
Electron photodetachment
Electronic excitation
Equilibrium solvation structures
Solvation dynamics
Surface states
Molecular dynamics
description New insights into equilibrium and dynamical aspects of electron photodetachment reactions in small water clusters were given. It focuses on assessing the effects of thermal and polarization fluctuations provided by three cluster environments with different extents of spatial confinement, on the microscopic mechanisms that drive the reaction. These fluctuations, in turn, determine the characteristics of the electron localization and the subsequent detachment following photoexcitation of the probe.
author Elola, María Dolores
Laria, Daniel Hector
author_facet Elola, María Dolores
Laria, Daniel Hector
author_sort Elola, María Dolores
title Solvation dynamics following electron photodetachment from l- in aqueous clusters
title_short Solvation dynamics following electron photodetachment from l- in aqueous clusters
title_full Solvation dynamics following electron photodetachment from l- in aqueous clusters
title_fullStr Solvation dynamics following electron photodetachment from l- in aqueous clusters
title_full_unstemmed Solvation dynamics following electron photodetachment from l- in aqueous clusters
title_sort solvation dynamics following electron photodetachment from l- in aqueous clusters
publishDate 2002
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219606_v117_n5_p2238_Elola
http://hdl.handle.net/20.500.12110/paper_00219606_v117_n5_p2238_Elola
work_keys_str_mv AT elolamariadolores solvationdynamicsfollowingelectronphotodetachmentfromlinaqueousclusters
AT lariadanielhector solvationdynamicsfollowingelectronphotodetachmentfromlinaqueousclusters
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