Solubility of two stable iminium salts in 12 polar solvents

Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Marschoff, Carlos Miguel, Rodríguez, Juan Bautista, Gros, Eduardo Gervasio
Publicado:	2002
Materias:	Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219568_v47_n6_p1337_Grande http://hdl.handle.net/20.500.12110/paper_00219568_v47_n6_p1337_Grande
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00219568_v47_n6_p1337_Grande
record_format	dspace
spelling	paper:paper_00219568_v47_n6_p1337_Grande2023-06-08T14:43:50Z Solubility of two stable iminium salts in 12 polar solvents Marschoff, Carlos Miguel Rodríguez, Juan Bautista Gros, Eduardo Gervasio Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated. Fil:Marschoff, C.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Rodríguez, J.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2002 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219568_v47_n6_p1337_Grande http://hdl.handle.net/20.500.12110/paper_00219568_v47_n6_p1337_Grande
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds
spellingShingle	Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds Marschoff, Carlos Miguel Rodríguez, Juan Bautista Gros, Eduardo Gervasio Solubility of two stable iminium salts in 12 polar solvents
topic_facet	Hydrolysis Infrared spectroscopy Nuclear magnetic resonance spectroscopy Solubility Solvents Synthesis (chemical) Temperature Water Iminium salts Physicochemical properties Polar solvents Organic compounds
description	Despite their biological importance, little is known about the physicochemical properties of iminium salts due to their high reactivity with water. Our group has synthesized several iminium salts that are unusually stable to hydrolysis. In the present work, solubility data are reported as a function of temperature for two of these compounds, namely, 8-acetamide-2,4,4,8-tetramethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate and 8-benzamide-2-phenyl-4,4,8-trimethyl-3-azabicyclo[3.3.1]non-2-ene perchlorate, in 12 different polar solvents. Thermodynamic quantities related to the solution process are calculated.
author	Marschoff, Carlos Miguel Rodríguez, Juan Bautista Gros, Eduardo Gervasio
author_facet	Marschoff, Carlos Miguel Rodríguez, Juan Bautista Gros, Eduardo Gervasio
author_sort	Marschoff, Carlos Miguel
title	Solubility of two stable iminium salts in 12 polar solvents
title_short	Solubility of two stable iminium salts in 12 polar solvents
title_full	Solubility of two stable iminium salts in 12 polar solvents
title_fullStr	Solubility of two stable iminium salts in 12 polar solvents
title_full_unstemmed	Solubility of two stable iminium salts in 12 polar solvents
title_sort	solubility of two stable iminium salts in 12 polar solvents
publishDate	2002
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219568_v47_n6_p1337_Grande http://hdl.handle.net/20.500.12110/paper_00219568_v47_n6_p1337_Grande
work_keys_str_mv	AT marschoffcarlosmiguel solubilityoftwostableiminiumsaltsin12polarsolvents AT rodriguezjuanbautista solubilityoftwostableiminiumsaltsin12polarsolvents AT groseduardogervasio solubilityoftwostableiminiumsaltsin12polarsolvents
_version_	1768542534968016896

Solubility of two stable iminium salts in 12 polar solvents

Ejemplares similares