Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system

The mechanical properties and glass-transition temperature within different thickness organic coatings made of diglycidyl ether of bisphenol A epoxy resin and 3-aminomethyl-3,5,5-trirnethylcyclohexylamine hardener are determined. The coatings are deposited on aluminum alloy (1050) substrates after d...

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Detalles Bibliográficos
Autores principales:	Goyanes, Silvia Nair, Roncaglia, Augusto José
Publicado:	2005
Materias:	Coating Epoxy-aluminum interphase Glass transition Resin Aluminum alloys Chemical analysis Differential scanning calorimetry Epoxy resins Interfaces (materials) Mechanical properties Degreasing Epoxy interface Metal interface Organic coatings polymer science
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v98_n2_p891_Goyanes http://hdl.handle.net/20.500.12110/paper_00218995_v98_n2_p891_Goyanes
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00218995_v98_n2_p891_Goyanes
record_format	dspace
spelling	paper:paper_00218995_v98_n2_p891_Goyanes2023-06-08T14:43:02Z Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system Goyanes, Silvia Nair Roncaglia, Augusto José Coating Epoxy-aluminum interphase Glass transition Resin Aluminum alloys Chemical analysis Differential scanning calorimetry Epoxy resins Glass transition Interfaces (materials) Mechanical properties Degreasing Epoxy interface Epoxy-aluminum interphase Metal interface Organic coatings polymer science The mechanical properties and glass-transition temperature within different thickness organic coatings made of diglycidyl ether of bisphenol A epoxy resin and 3-aminomethyl-3,5,5-trirnethylcyclohexylamine hardener are determined. The coatings are deposited on aluminum alloy (1050) substrates after degreasing. Dynamic mechanical thermal analysis and differential scanning calorimetry experiments are carried out on debonded coatings before and after the material from the opposed surface to the polymer/metal interface is removed by polishing. The results clearly show that the values of the physical and mechanical properties in those coatings depend on their thickness, but there is no gradient of properties within such coatings. Therefore, at a given thickness, those properties are homogeneous within the coating. To gain a better fundamental understanding of this behavior, a qualitative model involving the chemical reactions that take place at the epoxy/metal interface and the related diffusion phenomena is given. © 2005 Wiley Periodicals, Inc. Fil:Goyanes, S.N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Roncaglia, A.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2005 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v98_n2_p891_Goyanes http://hdl.handle.net/20.500.12110/paper_00218995_v98_n2_p891_Goyanes
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Coating Epoxy-aluminum interphase Glass transition Resin Aluminum alloys Chemical analysis Differential scanning calorimetry Epoxy resins Glass transition Interfaces (materials) Mechanical properties Degreasing Epoxy interface Epoxy-aluminum interphase Metal interface Organic coatings polymer science
spellingShingle	Coating Epoxy-aluminum interphase Glass transition Resin Aluminum alloys Chemical analysis Differential scanning calorimetry Epoxy resins Glass transition Interfaces (materials) Mechanical properties Degreasing Epoxy interface Epoxy-aluminum interphase Metal interface Organic coatings polymer science Goyanes, Silvia Nair Roncaglia, Augusto José Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system
topic_facet	Coating Epoxy-aluminum interphase Glass transition Resin Aluminum alloys Chemical analysis Differential scanning calorimetry Epoxy resins Glass transition Interfaces (materials) Mechanical properties Degreasing Epoxy interface Epoxy-aluminum interphase Metal interface Organic coatings polymer science
description	The mechanical properties and glass-transition temperature within different thickness organic coatings made of diglycidyl ether of bisphenol A epoxy resin and 3-aminomethyl-3,5,5-trirnethylcyclohexylamine hardener are determined. The coatings are deposited on aluminum alloy (1050) substrates after degreasing. Dynamic mechanical thermal analysis and differential scanning calorimetry experiments are carried out on debonded coatings before and after the material from the opposed surface to the polymer/metal interface is removed by polishing. The results clearly show that the values of the physical and mechanical properties in those coatings depend on their thickness, but there is no gradient of properties within such coatings. Therefore, at a given thickness, those properties are homogeneous within the coating. To gain a better fundamental understanding of this behavior, a qualitative model involving the chemical reactions that take place at the epoxy/metal interface and the related diffusion phenomena is given. © 2005 Wiley Periodicals, Inc.
author	Goyanes, Silvia Nair Roncaglia, Augusto José
author_facet	Goyanes, Silvia Nair Roncaglia, Augusto José
author_sort	Goyanes, Silvia Nair
title	Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system
title_short	Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system
title_full	Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system
title_fullStr	Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system
title_full_unstemmed	Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system
title_sort	variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system
publishDate	2005
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v98_n2_p891_Goyanes http://hdl.handle.net/20.500.12110/paper_00218995_v98_n2_p891_Goyanes
work_keys_str_mv	AT goyanessilvianair variationinphysicalandmechanicalpropertieswithcoatingthicknessinepoxydiaminealuminumsystem AT roncagliaaugustojose variationinphysicalandmechanicalpropertieswithcoatingthicknessinepoxydiaminealuminumsystem
_version_	1768543496906473472

Variation in physical and mechanical properties with coating thickness in epoxy-diamine-aluminum system

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