Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]

The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd-Gd separation of 7.16(1) Å. Magnetic susceptibility...

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Detalles Bibliográficos
Autores principales: Baggio, Ricardo F., Perec, Mireille
Publicado: 2001
Materias:
gadolinium
ligand
article
complex formation
crystal structure
magnetism
molecular dynamics
stereochemistry
synthesis
X ray crystallography
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v40_n14_p3623_Rizzi
http://hdl.handle.net/20.500.12110/paper_00201669_v40_n14_p3623_Rizzi
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00201669_v40_n14_p3623_Rizzi
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spelling paper:paper_00201669_v40_n14_p3623_Rizzi2023-06-08T14:40:29Z Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] Baggio, Ricardo F. Perec, Mireille gadolinium ligand article complex formation crystal structure magnetism molecular dynamics stereochemistry synthesis X ray crystallography The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd-Gd separation of 7.16(1) Å. Magnetic susceptibility and EPR measurements showed weak magnetic exchange coupling of the 3D type. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2001 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v40_n14_p3623_Rizzi http://hdl.handle.net/20.500.12110/paper_00201669_v40_n14_p3623_Rizzi
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic gadolinium
ligand
article
complex formation
crystal structure
magnetism
molecular dynamics
stereochemistry
synthesis
X ray crystallography
spellingShingle gadolinium
ligand
article
complex formation
crystal structure
magnetism
molecular dynamics
stereochemistry
synthesis
X ray crystallography
Baggio, Ricardo F.
Perec, Mireille
Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
topic_facet gadolinium
ligand
article
complex formation
crystal structure
magnetism
molecular dynamics
stereochemistry
synthesis
X ray crystallography
description The mononuclear gadolinium mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)] has been prepared and structurally characterized by X-ray crystallography. Two complex molecules are doubly bridged by H bonds between carboxylate and aqua ligands with a Gd-Gd separation of 7.16(1) Å. Magnetic susceptibility and EPR measurements showed weak magnetic exchange coupling of the 3D type.
author Baggio, Ricardo F.
Perec, Mireille
author_facet Baggio, Ricardo F.
Perec, Mireille
author_sort Baggio, Ricardo F.
title Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_short Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_full Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_fullStr Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_full_unstemmed Synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [Gd(CF3CO2)3(phen)2 (H2O)]
title_sort synthesis, crystal structure, and magnetic properties of the mixed-ligand complex [gd(cf3co2)3(phen)2 (h2o)]
publishDate 2001
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v40_n14_p3623_Rizzi
http://hdl.handle.net/20.500.12110/paper_00201669_v40_n14_p3623_Rizzi
work_keys_str_mv AT baggioricardof synthesiscrystalstructureandmagneticpropertiesofthemixedligandcomplexgdcf3co23phen2h2o
AT perecmireille synthesiscrystalstructureandmagneticpropertiesofthemixedligandcomplexgdcf3co23phen2h2o
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