Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group

A series of acyloxy derivatives of pyridoxine (1) have been prepared by transesterification reactions of 1 and ethyl carboxylates, catalyzed by several lipases. Moreover, acetylated derivatives of 1 were selectively deacetylated by enzymatic catalysis in organic media.

Detalles Bibliográficos
Autores principales:	Baldessari, Alicia, Mangone, Constanza Pía, Gros, Eduardo Gervasio
Publicado:	1998
Materias:	carboxylic acid derivative pyridoxine pyridoxine derivative triacylglycerol lipase acylation article carbon nuclear magnetic resonance catalysis deacylation esterification mass spectrometry proton nuclear magnetic resonance
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0018019X_v81_n12_p2407_Baldessari http://hdl.handle.net/20.500.12110/paper_0018019X_v81_n12_p2407_Baldessari
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_0018019X_v81_n12_p2407_Baldessari
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spelling	paper:paper_0018019X_v81_n12_p2407_Baldessari2023-06-08T14:39:08Z Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group Baldessari, Alicia Mangone, Constanza Pía Gros, Eduardo Gervasio carboxylic acid derivative pyridoxine pyridoxine derivative triacylglycerol lipase acylation article carbon nuclear magnetic resonance catalysis deacylation esterification mass spectrometry proton nuclear magnetic resonance A series of acyloxy derivatives of pyridoxine (1) have been prepared by transesterification reactions of 1 and ethyl carboxylates, catalyzed by several lipases. Moreover, acetylated derivatives of 1 were selectively deacetylated by enzymatic catalysis in organic media. Fil:Baldessari, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Mangone, C.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1998 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0018019X_v81_n12_p2407_Baldessari http://hdl.handle.net/20.500.12110/paper_0018019X_v81_n12_p2407_Baldessari
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	carboxylic acid derivative pyridoxine pyridoxine derivative triacylglycerol lipase acylation article carbon nuclear magnetic resonance catalysis deacylation esterification mass spectrometry proton nuclear magnetic resonance
spellingShingle	carboxylic acid derivative pyridoxine pyridoxine derivative triacylglycerol lipase acylation article carbon nuclear magnetic resonance catalysis deacylation esterification mass spectrometry proton nuclear magnetic resonance Baldessari, Alicia Mangone, Constanza Pía Gros, Eduardo Gervasio Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group
topic_facet	carboxylic acid derivative pyridoxine pyridoxine derivative triacylglycerol lipase acylation article carbon nuclear magnetic resonance catalysis deacylation esterification mass spectrometry proton nuclear magnetic resonance
description	A series of acyloxy derivatives of pyridoxine (1) have been prepared by transesterification reactions of 1 and ethyl carboxylates, catalyzed by several lipases. Moreover, acetylated derivatives of 1 were selectively deacetylated by enzymatic catalysis in organic media.
author	Baldessari, Alicia Mangone, Constanza Pía Gros, Eduardo Gervasio
author_facet	Baldessari, Alicia Mangone, Constanza Pía Gros, Eduardo Gervasio
author_sort	Baldessari, Alicia
title	Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group
title_short	Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group
title_full	Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group
title_fullStr	Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group
title_full_unstemmed	Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group
title_sort	lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-b6 group
publishDate	1998
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0018019X_v81_n12_p2407_Baldessari http://hdl.handle.net/20.500.12110/paper_0018019X_v81_n12_p2407_Baldessari
work_keys_str_mv	AT baldessarialicia lipasecatalyzedacylationanddeacylationreactionsofpyridoxineamemberofvitaminb6group AT mangoneconstanzapia lipasecatalyzedacylationanddeacylationreactionsofpyridoxineamemberofvitaminb6group AT groseduardogervasio lipasecatalyzedacylationanddeacylationreactionsofpyridoxineamemberofvitaminb6group
_version_	1768541968596467712

Lipase-catalyzed acylation and deacylation reactions of pyridoxine, a member of vitamin-B6 group

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