Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds
Metal-assisted trifluoromethylation and perfluoroalkylation reactions are probably one of the first approaches employed to achieve fluoroalkyl-group substitutions of organic substrates through the use of metals such as copper. Fluoroalkylation reactions of both aromatic and aliphatic substrates invo...
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00108545_v285_n_p76_Lantano http://hdl.handle.net/20.500.12110/paper_00108545_v285_n_p76_Lantano |
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paper:paper_00108545_v285_n_p76_Lantano2023-06-08T14:34:42Z Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds Bonesi, Sergio Mauricio Fluoroalkylation of aromatics Metal-assisted trifluoromethylation Trifluoromethylation by metal-organic species Metal-assisted trifluoromethylation and perfluoroalkylation reactions are probably one of the first approaches employed to achieve fluoroalkyl-group substitutions of organic substrates through the use of metals such as copper. Fluoroalkylation reactions of both aromatic and aliphatic substrates involving the employment of perfluoroalkyl halides RfX in conjunction with metallic species, and nucleophilic fluoroalkylating reagents in the presence of metals or organometallic species will be studied. Fluoroalkylation reactions utilizing electrophilic fluoroalkylating reagents in the presence of transition metals or trifluoromethylthiolation reactions will not be the subject of this article. Recently emerging literature (2011-present), with special emphasis on updates from previous review articles on the metal-mediated fluoroalkylation of aromatic substrates will be dealt with. © 2014 Elsevier B.V. Fil:Bonesi, S.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2015 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00108545_v285_n_p76_Lantano http://hdl.handle.net/20.500.12110/paper_00108545_v285_n_p76_Lantano |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Fluoroalkylation of aromatics Metal-assisted trifluoromethylation Trifluoromethylation by metal-organic species |
| spellingShingle |
Fluoroalkylation of aromatics Metal-assisted trifluoromethylation Trifluoromethylation by metal-organic species Bonesi, Sergio Mauricio Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds |
| topic_facet |
Fluoroalkylation of aromatics Metal-assisted trifluoromethylation Trifluoromethylation by metal-organic species |
| description |
Metal-assisted trifluoromethylation and perfluoroalkylation reactions are probably one of the first approaches employed to achieve fluoroalkyl-group substitutions of organic substrates through the use of metals such as copper. Fluoroalkylation reactions of both aromatic and aliphatic substrates involving the employment of perfluoroalkyl halides RfX in conjunction with metallic species, and nucleophilic fluoroalkylating reagents in the presence of metals or organometallic species will be studied. Fluoroalkylation reactions utilizing electrophilic fluoroalkylating reagents in the presence of transition metals or trifluoromethylthiolation reactions will not be the subject of this article. Recently emerging literature (2011-present), with special emphasis on updates from previous review articles on the metal-mediated fluoroalkylation of aromatic substrates will be dealt with. © 2014 Elsevier B.V. |
| author |
Bonesi, Sergio Mauricio |
| author_facet |
Bonesi, Sergio Mauricio |
| author_sort |
Bonesi, Sergio Mauricio |
| title |
Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds |
| title_short |
Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds |
| title_full |
Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds |
| title_fullStr |
Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds |
| title_full_unstemmed |
Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds |
| title_sort |
advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds |
| publishDate |
2015 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00108545_v285_n_p76_Lantano http://hdl.handle.net/20.500.12110/paper_00108545_v285_n_p76_Lantano |
| work_keys_str_mv |
AT bonesisergiomauricio advancesinmetalassistednonelectrophilicfluoroalkylationreactionsoforganiccompounds |
| _version_ |
1768546473614508032 |