The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis

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Inner projections of the polarization propagator were used to study the indirect through-space transmission of the Fermi contact term of CF couplings via a CX (X = F, H) intermediate bond. When X = H a large capability for transmitting this component is observed. But for X = F a notable inhibition o...

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Autores principales: Natiello, Mario Alberto, Contreras, Rubén Horacio
Publicado: 1984
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00092614_v104_n6_p568_Natiello
http://hdl.handle.net/20.500.12110/paper_00092614_v104_n6_p568_Natiello
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00092614_v104_n6_p568_Natiello
record_format dspace
spelling paper:paper_00092614_v104_n6_p568_Natiello2023-06-08T14:33:39Z The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis Natiello, Mario Alberto Contreras, Rubén Horacio Inner projections of the polarization propagator were used to study the indirect through-space transmission of the Fermi contact term of CF couplings via a CX (X = F, H) intermediate bond. When X = H a large capability for transmitting this component is observed. But for X = F a notable inhibition of this transmission mechanism is observed. The role of the fluorine lone pairs in this behaviour is discussed. © 1984. Fil:Natiello, M.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Contreras, R.H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1984 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00092614_v104_n6_p568_Natiello http://hdl.handle.net/20.500.12110/paper_00092614_v104_n6_p568_Natiello
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Inner projections of the polarization propagator were used to study the indirect through-space transmission of the Fermi contact term of CF couplings via a CX (X = F, H) intermediate bond. When X = H a large capability for transmitting this component is observed. But for X = F a notable inhibition of this transmission mechanism is observed. The role of the fluorine lone pairs in this behaviour is discussed. © 1984.
author Natiello, Mario Alberto
Contreras, Rubén Horacio
spellingShingle Natiello, Mario Alberto
Contreras, Rubén Horacio
The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis
author_facet Natiello, Mario Alberto
Contreras, Rubén Horacio
author_sort Natiello, Mario Alberto
title The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis
title_short The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis
title_full The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis
title_fullStr The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis
title_full_unstemmed The through-space transmission of 13C19F coupling constants via an intermediate bond: A polarization propagator analysis
title_sort through-space transmission of 13c19f coupling constants via an intermediate bond: a polarization propagator analysis
publishDate 1984
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00092614_v104_n6_p568_Natiello
http://hdl.handle.net/20.500.12110/paper_00092614_v104_n6_p568_Natiello
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AT natiellomarioalberto throughspacetransmissionof13c19fcouplingconstantsviaanintermediatebondapolarizationpropagatoranalysis
AT contrerasrubenhoracio throughspacetransmissionof13c19fcouplingconstantsviaanintermediatebondapolarizationpropagatoranalysis
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