Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses

By the use of three differently labeled penta-O-benzoyl-D-glucopyranoses, it was possible to detect a partial, benzoyl migration from O-4 to O-6 during the ammonolysis of penta-benzoyl-D-O-glucopyranose in isopropyl alcohol. When the same reaction was applied to a penta-O-benzoyl-aldehydo-D-glucose...

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Autores principales: Lezerovich, Alberto, Gros, Eduardo Gervasio, Sproviero, Jorge Félix, Deulofeu, Venancio
Publicado: 1967
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v4_n1_p1_Lezerovich
http://hdl.handle.net/20.500.12110/paper_00086215_v4_n1_p1_Lezerovich
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spelling paper:paper_00086215_v4_n1_p1_Lezerovich2023-06-08T14:33:08Z Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses Lezerovich, Alberto Gros, Eduardo Gervasio Sproviero, Jorge Félix Deulofeu, Venancio By the use of three differently labeled penta-O-benzoyl-D-glucopyranoses, it was possible to detect a partial, benzoyl migration from O-4 to O-6 during the ammonolysis of penta-benzoyl-D-O-glucopyranose in isopropyl alcohol. When the same reaction was applied to a penta-O-benzoyl-aldehydo-D-glucose derivative, a partial migration of a benzoyl group from O-2 to O-6 was also encountered. © 1967. Fil:Lezerovich, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Sproviero, J.F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deulofeu, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1967 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v4_n1_p1_Lezerovich http://hdl.handle.net/20.500.12110/paper_00086215_v4_n1_p1_Lezerovich
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description By the use of three differently labeled penta-O-benzoyl-D-glucopyranoses, it was possible to detect a partial, benzoyl migration from O-4 to O-6 during the ammonolysis of penta-benzoyl-D-O-glucopyranose in isopropyl alcohol. When the same reaction was applied to a penta-O-benzoyl-aldehydo-D-glucose derivative, a partial migration of a benzoyl group from O-2 to O-6 was also encountered. © 1967.
author Lezerovich, Alberto
Gros, Eduardo Gervasio
Sproviero, Jorge Félix
Deulofeu, Venancio
spellingShingle Lezerovich, Alberto
Gros, Eduardo Gervasio
Sproviero, Jorge Félix
Deulofeu, Venancio
Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses
author_facet Lezerovich, Alberto
Gros, Eduardo Gervasio
Sproviero, Jorge Félix
Deulofeu, Venancio
author_sort Lezerovich, Alberto
title Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses
title_short Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses
title_full Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses
title_fullStr Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses
title_full_unstemmed Reaction of ammonia with some acetylated and benzoylated monosaccharides. Part XI. Intramolecular migration of O-benzoyl groups in the partial ammonolysis of penta-O-benzoyl-D-glucoses
title_sort reaction of ammonia with some acetylated and benzoylated monosaccharides. part xi. intramolecular migration of o-benzoyl groups in the partial ammonolysis of penta-o-benzoyl-d-glucoses
publishDate 1967
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00086215_v4_n1_p1_Lezerovich
http://hdl.handle.net/20.500.12110/paper_00086215_v4_n1_p1_Lezerovich
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