Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate
X-ray single crystal analysis sheds further light on the structure of this new iminium salt. ATABNEP crystallizes in the monoclinic system, space group P21 and shows a very short value for the C-N distance in the iminium group, thus suggesting that the contribution of the carbonium ion form in this...
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1987
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00084042_v65_n9_p2000_Viturro http://hdl.handle.net/20.500.12110/paper_00084042_v65_n9_p2000_Viturro |
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paper:paper_00084042_v65_n9_p2000_Viturro2025-07-30T17:15:04Z Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate Single crystals Crystal and molecular structure Iminium Iminium salts Monoclinic systems Space Groups X-ray single-crystal analysis Crystal structure X-ray single crystal analysis sheds further light on the structure of this new iminium salt. ATABNEP crystallizes in the monoclinic system, space group P21 and shows a very short value for the C-N distance in the iminium group, thus suggesting that the contribution of the carbonium ion form in this particular case is much lower than usual, a fact that can be considered a rationale for the reluctance of ATABNEP to undergo hydrolysis. 1987 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00084042_v65_n9_p2000_Viturro http://hdl.handle.net/20.500.12110/paper_00084042_v65_n9_p2000_Viturro |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Single crystals Crystal and molecular structure Iminium Iminium salts Monoclinic systems Space Groups X-ray single-crystal analysis Crystal structure |
| spellingShingle |
Single crystals Crystal and molecular structure Iminium Iminium salts Monoclinic systems Space Groups X-ray single-crystal analysis Crystal structure Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate |
| topic_facet |
Single crystals Crystal and molecular structure Iminium Iminium salts Monoclinic systems Space Groups X-ray single-crystal analysis Crystal structure |
| description |
X-ray single crystal analysis sheds further light on the structure of this new iminium salt. ATABNEP crystallizes in the monoclinic system, space group P21 and shows a very short value for the C-N distance in the iminium group, thus suggesting that the contribution of the carbonium ion form in this particular case is much lower than usual, a fact that can be considered a rationale for the reluctance of ATABNEP to undergo hydrolysis. |
| title |
Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate |
| title_short |
Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate |
| title_full |
Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate |
| title_fullStr |
Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate |
| title_full_unstemmed |
Crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate |
| title_sort |
crystal and molecular structure of 8-acetamido-2,4,4,8-tetramethyl-3-azaniumbicyclo[3.3.l]non-2-epneer chlorate |
| publishDate |
1987 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00084042_v65_n9_p2000_Viturro http://hdl.handle.net/20.500.12110/paper_00084042_v65_n9_p2000_Viturro |
| _version_ |
1840322131537166336 |