Alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali

1. The action of alkali in alcohol solutions upon skimmianine (β-fagarine) and γ-fagarine has been found to consist of an interchange between the γ methoxyl of these alkaloids and the alkoxyl group of the solvent alcohol. 2. The new alkoxy analogs and several of their derivatives have been described...

Descripción completa

Detalles Bibliográficos
Autores principales: Berinzaghi, Blanca G., Deulofeu, Venancio, Labriola, Rafael A., Muruzabal, Angela
Publicado: 1943
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v65_n7_p1357_Berinzaghi
http://hdl.handle.net/20.500.12110/paper_00027863_v65_n7_p1357_Berinzaghi
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00027863_v65_n7_p1357_Berinzaghi
record_format dspace
spelling paper:paper_00027863_v65_n7_p1357_Berinzaghi2023-06-08T14:22:55Z Alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali Berinzaghi, Blanca G. Deulofeu, Venancio Labriola, Rafael A. Muruzabal, Angela 1. The action of alkali in alcohol solutions upon skimmianine (β-fagarine) and γ-fagarine has been found to consist of an interchange between the γ methoxyl of these alkaloids and the alkoxyl group of the solvent alcohol. 2. The new alkoxy analogs and several of their derivatives have been described. 3. The reconversion of the new alkoxy analogs into the original alkaloids by action of alkali in methanol has been observed. 4. Possible mechanisms of the changes have been discussed. © 1943, American Chemical Society. All rights reserved. Fil:Berinzaghi, B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deulofeu, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Labriola, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Muruzabal, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1943 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v65_n7_p1357_Berinzaghi http://hdl.handle.net/20.500.12110/paper_00027863_v65_n7_p1357_Berinzaghi
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description 1. The action of alkali in alcohol solutions upon skimmianine (β-fagarine) and γ-fagarine has been found to consist of an interchange between the γ methoxyl of these alkaloids and the alkoxyl group of the solvent alcohol. 2. The new alkoxy analogs and several of their derivatives have been described. 3. The reconversion of the new alkoxy analogs into the original alkaloids by action of alkali in methanol has been observed. 4. Possible mechanisms of the changes have been discussed. © 1943, American Chemical Society. All rights reserved.
author Berinzaghi, Blanca G.
Deulofeu, Venancio
Labriola, Rafael A.
Muruzabal, Angela
spellingShingle Berinzaghi, Blanca G.
Deulofeu, Venancio
Labriola, Rafael A.
Muruzabal, Angela
Alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali
author_facet Berinzaghi, Blanca G.
Deulofeu, Venancio
Labriola, Rafael A.
Muruzabal, Angela
author_sort Berinzaghi, Blanca G.
title Alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali
title_short Alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali
title_full Alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali
title_fullStr Alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali
title_full_unstemmed Alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali
title_sort alkoxyl interchange by γ-alkoxyquinoline derivatives in alcoholic alkali
publishDate 1943
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v65_n7_p1357_Berinzaghi
http://hdl.handle.net/20.500.12110/paper_00027863_v65_n7_p1357_Berinzaghi
work_keys_str_mv AT berinzaghiblancag alkoxylinterchangebygalkoxyquinolinederivativesinalcoholicalkali
AT deulofeuvenancio alkoxylinterchangebygalkoxyquinolinederivativesinalcoholicalkali
AT labriolarafaela alkoxylinterchangebygalkoxyquinolinederivativesinalcoholicalkali
AT muruzabalangela alkoxylinterchangebygalkoxyquinolinederivativesinalcoholicalkali
_version_ 1768543110515654656

Ejemplares similares